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Current Issue vol. 36, No. 5, 2025

 

Oligo(ethylene glycol) chains (OEGs) can improve analytical responses, perfecting sensing systems as a masterpiece. Although OEGs have been used in sensing systems for more than 25 years, they did not receive proper attention. But now, OEGs will emerge as useful tools to the development of novel or existing sensing systems. Eleven roles played by the OEGs in the sensing systems are known, but more might be discovered. Details are presented in the Review Roles of Oligo(ethylene glycol) to Improve Sensing Systems by Taciana H. Kunst, Paulo Henrique Menezes and Ana Paula S. Paim on e-20250003.


Cover Article
J. Braz. Chem. Soc. 2025, 36(5), e-20250003, 1-9

Roles of Oligo(ethylene glycol) to Improve Sensing Systems

Taciana H. Kunst; Paulo Henrique Menezes ; Ana Paula S. Paim

How to cite this article

Oligo(ethylene glycol) chains (OEGs) can improve analytical responses, perfecting sensing systems as a masterpiece. Although OEGs have been used in sensing systems for more than 25 years, they did not receive proper attention. But now, OEGs will emerge as useful tools to the development of novel or existing sensing systems. Eleven roles played by the OEGs in the sensing systems are known, but more might be discovered. Details are presented in the Review Roles of Oligo(ethylene glycol) to Improve Sensing Systems by Taciana H. Kunst, Paulo Henrique Menezes and Ana Paula S. Paim on e-20250003.

https://dx.doi.org/10.21577/0103-5053.20250003

Published online: January  7, 2025
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Editorial J. Braz. Chem. Soc. 2025, 36(5), e-20250039, 1-2

The Role of the Journal of the Brazilian Chemical Society (JBCS) in Advancing Scientific Research in Northeastern Brazil

Giovanna Machado

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https://dx.doi.org/10.21577/0103-5053.20250039

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Review J. Braz. Chem. Soc. 2025, 36(5), e-20250003, 1-9

Roles of Oligo(ethylene glycol) to Improve Sensing Systems

Taciana H. Kunst; Paulo Henrique Menezes ; Ana Paula S. Paim

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Oligo(ethylene glycol) (OEG) can play several roles in sensing systems. The OEG-containing sensing systems are shown to be advantageous as the OEG improves their performance in the analysis of distinct analytes by different techniques.

https://dx.doi.org/10.21577/0103-5053.20250003

Published online: January 7, 2025

 

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Articles J. Braz. Chem. Soc. 2025, 36(5), e-20240194, 1-10

Analysis of Cocaine, Benzoylecgonine, and Ecgonine Methyl Ester in Hair Strands Via Matrix-Assisted Laser Desorption Ionization Mass Spectrometry (MALDI-MS)

Patrícia Donateli; Nayara A. dos Santos ; Sébastien Charneau; Marcelo V. de Sousa; Bruno D. Sabino; Wanderson Romão

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MALDI(+)TOF MS (matrix-assisted laser-desorption and ionization time-of-flight mass spectrometry) for the rapid detection of cocaine (COC), benzoylecgonine (BZE), and ecgonine methyl ester (EME) in hair strands.

https://dx.doi.org/10.21577/0103-5053.20240194

Published online: October 7, 2024

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20240195, 1-11

Influence of Current Density and Chloride Concentration on the Electrooxidation of Ammonia and Organic Matter in Ammonia-Laden Effluents

Caroline R. S. Brigido ; Flávio A. Lemos; Iranildes D. dos Santos ; Achilles J. B. Dutra

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The study aimed to degrade ammonia nitrogen and organic matter in effluent generated at a port terminal used for fertilizer storage. The results indicated removal of 99.99% of N-NH3 and 75.60% of total organic carbon (TOC).

https://dx.doi.org/10.21577/0103-5053.20240195

Published online: October 8, 2024

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20240196, 1-16

Volatile and Non-Volatile Compounds Profiling of Brazilian Pitanga (Eugenia uniflora L.) Varieties During Ripening using Gas Chromatography-Mass Spectrometry Approach

Grazieli B. Pascoal ; Silvia L. R. Meza ; Eric C. Tobaruela ; Rodrigo Cezar Franzon; Isabel L. Massaretto; Eduardo Purgatto

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The Brazilian pitanga fruits exhibited volatile compounds such as esters, terpenes and aldehydes, with β-elemene, E-germacrene and ethyl acetate being the most abundant. Additionally, 124 polar and non-polar metabolites were identified, notably including fatty acids, sugars and terpenes, which possess potential health-promoting effects.

https://dx.doi.org/10.21577/0103-5053.20240196

Published online: October 11, 2024

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20240197, 1-12

Dye Contaminant Removal: Adsorption on Thermoplastic Starch/Kraft Lignin Composites and Photodegradation

Amanda S. M. de Freitas ; Jéssica S. Rodrigues ; Stefanny F. Amaro ; Beatriz M. Ramos; Marystela Ferreira

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Experimental steps: adsorption of the dyes used (methylene blue (MB) and methyl orange (MO)) present in the solution in thermoplastic starch films (TPS) and TPS/kraft lignin (TPS-KL) (a), followed by desorption of the dyes present in the films in water (b), and subsequent remediation with exposure to photodegradation of the dyes desorbed in water (c).

https://dx.doi.org/10.21577/0103-5053.20240197

Published online: October 11, 2024

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20240198, 1-10

Synthesis and Evaluation of Biological Activities of Thieno-[2,3-d]-pyrimidine Derivatives

Yue Guo ; Chenglu Qian; Rongrong Yang; Zhongfei Han; Guoxiang Sun ; Yaquan Sun

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Twenty three thiophene[2,3-d]pyrimidine derivatives were synthesized by a 3-step reaction, and the bioactivity of the synthesized compounds was evaluated by breast cancer cell MDA-MB-231.

https://dx.doi.org/10.21577/0103-5053.20240198

Published online: October 11, 2024

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20240199, 1-10

The Influence of the Acyl Side Chain on Pyrene Excimer Formation as a Model for Asphaltene Aggregation

Suyane D. S. de Alvarenga; Simon J. Garden; Josué S. B. Forero; Raquel S. P. Teixeira; Rodrigo S. Souza; Yan M. H. Gonçalves; Bruno A. C. Horta; Javier A. G. Gomez; Luiz H. C. dos Santos; Emerson S. Ribeiro ; Rodrigo J. Corrêa

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Acyl pyrenes as models for asphaltene aggregation.

https://dx.doi.org/10.21577/0103-5053.20240199

Published online: October 11, 2024

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20240200, 1-21

Synthesis, Antileishmanial Activity, and in silico Study of 2-Hydroxy‑3‑(1,2,3‑triazolyl)propyl Vanillin Derivatives

Samira S. Santiago ; Camila S. Freitas ; Adilson V. Costa ; Mariana B. de Oliveira ; Aidene F. C. Faria ;
William S. Belarmino ; Gisely F. Moura ; Nayara A. dos Santos ; Wanderson Romão ; Valdemar Lacerda Júnior ;
Fabrício M. de Oliveira ; Osmair V. Oliveira; Eduardo A. F. Coelho ; Róbson R. Teixeira

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The synthesis, antileishmanial assay, and in silico analysis of twenty 2-hydroxy-3-(1,2,3-triazolyl)propyl vanillin derivatives are reported.

https://dx.doi.org/10.21577/0103-5053.20240200

Published online: October 18, 2024

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20240201, 1-10

Novel Terpene-Reinforced Photopolymerizable Resins Derived from Methacrylate Salts of Imidazole

Ilária M. S. Lins ; Anderson G. Vieira ; Rubson P. S. Ribeiro ; Dayane K. D. N. Santos ; Larissa G. Maciel ; Petrus A. Santa-Cruz ; Severino Alves Júnior ; Janaína V. dos Anjos

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This study explores 3D printable resin blends with terpene additives, yielding fifteen formulations. These resins hold promise for drug delivery and the fabrication of biomedical devices.

https://dx.doi.org/10.21577/0103-5053.20240201

Published online: October 23, 2024

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20240202, 1-14

Exploring the Potential of Waste Biomass from the Brazilian Legal Amazon in Bioproducts Production: a Comprehensive Analysis and Promising Perspectives

Mariana S. Borges ; Jéssyka R. Santos ; Marcelo M. Pedroza ; Magale K. D. Rambo ; Daniel B. Assumpção ;
Clarissa P. Frizzo ; Robert A. Burrow ; Elisandra Scapin

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Residual biomass from the Legal Amazon was used in a slow pyrolysis process. The biochars showed potential for carbon sequestration and contaminant adsorption, while bio-oils, containing phenols and furans, could serve as raw materials in the chemical industry.

https://dx.doi.org/10.21577/0103-5053.20240202

Published online: October 24, 2024

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20240216, 1-16

Computational and Experimental Study of PVA with F127 and Citric Acid for Electrospinning

Ariane Regina S. Rossin; Vinicius Martinelli; Ernani A. Basso ; Mariana S. Gibin; Vitor S. Zanuto; Bruno Henrique Vilsinski ;
Eduardo Radovanovic ; Wilker Caetano; Douglas C. Dragunski

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The conformation of polymer chains in solution and interactions with additional components can be studied computationally to improve electrospinning parameters.

https://dx.doi.org/10.21577/0103-5053.20240216

Published online: November 26, 2024

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20240218, 1-7

Higenamine Detection and Metabolism Study Using High-Performance Liquid Chromatography Coupled to AgIII-Luminol Chemiluminescence

Haoran Wang; Hanyu Sha; Mengying Liu; Hongmei Shi; Li Ma

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Detection method of higenamine in food and urine and metabolism study.

https://dx.doi.org/10.21577/0103-5053.20240218

Published online: December 2, 2024

 

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Total access: 491


J. Braz. Chem. Soc. 2025, 36(5), e-20240219, 1-16

Study of the Chemical Diversity in Spondias tuberosa Leaves During the Phenological Evolution Stages: Metabolomic and Chemometric Approaches Associated with Antioxidant and Antiglycant Activities

Francisco Wendell M. do Nascimento; Tamyris A. Gondim; Paulo R. V. Ribeiro; Maria Auxiliadora C. de Lima; Viseldo R. de Oliveira; João Francisco Câmara Neto; Maria Elenir N. P. Ribeiro; Anna Beatriz S. Ferrari; Maria Luiza Zeraik ; Jhonyson A. C. Guedes ; Guilherme J. Zocolo

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Evaluation of chemodiversity, antioxidant and antiglycant activities of Spondias tuberosa leaves during different stages of plant development.

https://dx.doi.org/10.21577/0103-5053.20240219

Published online: December 6, 2024

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20240226, 1-11

Sensitive Determination of Bisphenol A In Urine Using Automated Solid-Phase Extraction Followed by LC-MS/MS Analysis: Application to a Human Biomonitoring Study in Brazil

Camila F. de Souza ; Giovana P. Peteffi; Cloé D. Loredo; Marcos F. Bastiani; Amanda P. Bondan; Giovanna S. Grassi;
Carolina W. Ferrareze; Paola Winter; Roberta Z. Hahn; Marina V. Antunes; Rafael Linden

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Determination of bisphenol A in urine samples using automated solid-phase extraction followed by liquid chromatography-tandem mass spectroscopy (LC-MS/MS) analysis.

https://dx.doi.org/10.21577/0103-5053.20240226

Published online: December 20, 2024

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20240227, 1-9

Extracts from Tissue Cultures of Crotalaria spp. as Potential Natural Alternative for Controling Root-Knot Nematodes

Amanda P. Honório; Daiane E. Blank; Antonio J. Demuner ; Gustavo S. F. Souza ; Dalila S. Buonicontro; Eduardo V. V. Varejão ; Guilherme J. Zocolo ; Jhonyson A. C. Guedes ; Maria J. M. Firmino; Jilma L. B. R. D. Carvalho; Marcelo H. Santos; Daniele V. Faria; Lorena M. Vieira; Wagner C. Otoni; Franklin J. Machado

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Crotalaria juncea and Crotalaria ochroleuca were cultivated in vitro and the extracts from the callus exhibited high toxicity against Meloidogyne javanica. This effect could be phenolic compounds, alkaloids and flavonoids contents identified in these extracts.

https://dx.doi.org/10.21577/0103-5053.20240227

Published online: December 20, 2024

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20250001, 1-10

Chitosan Pretreatment: Evidence of Enhanced Mechanical Stability and Adsorption Capacity to Produce a Hybrid Material

Sueslley G. G. Rodrigues; Gisele S. Lopes ; Elisane Longhinotti ; Izaura C. N. Diógenes

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A sustainable hybrid material composed of chitosan biopolymer incorporated with an iron complex was developed for the effective detection of heterocyclic aromatic amines (HAAs), which are possible carcinogens formed during food heat processing.

https://dx.doi.org/10.21577/0103-5053.20250001

Published online: January 7, 2025

 

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Total access: 378


J. Braz. Chem. Soc. 2025, 36(5), e-20250006, 1-5

Sustainable Water Management for Steam Generation in Sugarcane Biorefineries: Applying PCA and MST Clustering in Sample Analysis

Érik Geraldo S. Souza ; Fabiola M. V. Pereira

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Our study on sustainable water management for steam generation in sugarcane biorefineries utilized unsupervised methods such as principal component analysis (PCA) and minimum spanning tree (MST) to assess water quality, providing valuable insights for optimizing bioenergy efficiency and sustainability.

https://dx.doi.org/10.21577/0103-5053.20250006

Published online: January 10, 2025

 

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Total access: 440


J. Braz. Chem. Soc. 2025, 36(5), e-20250007, 1-7

A New Non-Cyanogenic Cyanoglycoside with Promising α-Glycosidase Inhibitory Activity from the Roots of Cordia trichotoma

Késya A. D. Rocha ; Francisca R. S. Lopes; Francisco C. L. Pinto ; Francisco M. G. N. Pinheiro ; Samuel P. D. Marques ;
Maria Teresa S. Trevisan ; Edilberto R. Silveira ; Otília D. L. Pessoa ; Gilvandete M. P. Santiago

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Six non-cyanogenic cyanoglycosides, three of which are new, were isolated from the roots of Cordia trichotoma. The new highlighted compound (3) showed a promising α-glycosidase inhibitory activity.

https://dx.doi.org/10.21577/0103-5053.20250007

Published online: January 13, 2025

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20250009, 1-9

Use of Greenhouse Cell for Rhodamine B (RhB) Removal

Mokhtar Djehiche ; Marwa Bachiri; Nedjma Lahmar

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Solar thermal heating is an efficient and environmentally friendly method of heat generation, as it does not produce byproducts typically associated with artificial heating processes.

https://dx.doi.org/10.21577/0103-5053.20250009

Published online: January 17, 2025

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20250010, 1-9

A Spectrophotometric Study of the Interaction of Quercetin and Tannic Acid with Mimetic Systems of Cancerous and Healthy Cells

Pablo A. Oliveira ; Leandro A. Mendes ; Vitor O. Silva ; Paulo V. Scarparo ; Layra C. Conceição ; Pedro I. S. Maia ; Jéferson A. Moreto ; Natália B. L. Slade

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Spectrophotometric study of the interaction between quercetin and tannic acid with model membranes of healthy and cancer cells.

https://dx.doi.org/10.21577/0103-5053.20250010

Published online: January 20, 2025

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20250011, 1-8

Evaluation of the Uncertainty in the Measurement of Nanoparticle Size and Concentration by Single Particle Inductively Coupled Plasma Mass Spectrometry Technique

Adriana N. Geraldes ; Marcos A. Hortellani ; Maria Elisa C. M. Rostelato; Jorge E. S. Sarkis

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The identification and quantification of sources contributing to measurement uncertainties were evaluated using single-particle inductively coupled plasma mass spectrometry (sp-ICP-MS) with National Institute of Standards and Technology (NIST) reference material RM 8017.

https://dx.doi.org/10.21577/0103-5053.20250011

Published online: January 20, 2025

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20250012, 1-12

Drug Repurposing Strategy to Develop New AZT Derivatives Targeting SARS‑CoV-2 Mpro: Synthesis, Computational Studies, and Enzymatic Evaluation

Pedro A. B. Morais ; Natália A. Guedes; Caroline S. Fontes; Poliana A. R. Gazolla; Heberth de Paula; Walter C. C. Bigui;
Wanderson Romão ; Gabriela V. Costa; Adilson V. Costa ; Vagner T. de Queiroz; Valdemar Lacerda Júnior

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Synthesis and inhibitory activity against main protease of SARS-CoV-2 of AZT (3'-azido-3'-deoxythymidine) 1,2,3-triazole derivatives supported by molecular dynamics.

https://dx.doi.org/10.21577/0103-5053.20250012

Published online: January 22, 2025

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20250014, 1-7

Influence of Adding High Flash Point, Special Jet Fuel for Brazilian Navy (QAV-5), in Brazilian Marine Gasoil (ODM), on Fuel Viscosity, Specific Gravity, Cetane Index and Lubricity

Camila R. Louzeiro; Cristiane G. de Souza; Débora F. de Andrade; Luiz A. d'Avila

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Mixture of marine diesel oil with aviation kerosene undergoes accelerated oxidation in an oven to analyze its physical-chemical properties to assess whether it can be used on Brazilian navy ships without harm.

https://dx.doi.org/10.21577/0103-5053.20250014

Published online: January 24, 2025

 

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J. Braz. Chem. Soc. 2025, 36(5), e-20250015, 1-13

Analysis of Pesticides by Ultra-High Performance Liquid Chromatography in Combination with High Resolution Mass Spectrometry (UPLC-Orbitrap MS): Case Study for Application on River Water Samples in Vietnam

Nam Vu Duc ; Thuy Minh Le; Xuyen Nguyen Thi; Hoi Bui Van; Cam Tu Vu; Hong An Vu Thi; Dinh Binh Chu

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Analysis of screening and quantification for 118 pesticides by ultra-high performance liquid chromatography in combination with high resolution mass spectrometry (UPLC-Orbitrap MS).

https://dx.doi.org/10.21577/0103-5053.20250015

Published online: January 29, 2025

 

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Short Report J. Braz. Chem. Soc. 2025, 36(5), e-20250002, 1-5

One-Pot Sodium Azide-Free Synthesis of Aryl Azides from Anilines

Leonardo G. C. de Moraes ; Maria Cristina B. Guidinele; Vitor F. Ferreira ; David R. da Rocha

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Development of a one-pot methodology for the synthesis of aryl azides maintaining anilines as a molecular framework without the need to use sodium azide.

https://dx.doi.org/10.21577/0103-5053.20250002

Published online: January 7, 2025

 

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Online version ISSN 1678-4790 Printed version ISSN 0103-5053
Journal of the Brazilian Chemical Society
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University of Campinas - UNICAMP
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