Recent Papers - Machine Learning Special Issue
Reviews/Accounts - last 5 years
It Is Necessary to Resist
Angela Steinauer; Anna M. Butterfield; Anthony Linden; Agustin Molina-Ontario; David C. Buck; Robert W. Cotta; Luis Echegoyen; Kim K. Baldridge; Jay S. Siegel
How to cite this articleThe number of petals on a flower can be key to its taxonomy and properties, so too the number of thiophenyl groups on a corannulene imbue it with color, radiance and (electron) attractiveness. Each phenylthio derivative (n = 0-10) presents like a flower in a bouquet, assembling a veritable anthology of aromatics. Stemming from this chemical florilegium are principle additivity parameters useful for predicting the character of future corannulene-based inflorescence. Details are presented in the Article Tunable Photochemical/Redox Properties of (Phenylthio)ncorannulenes: Application to a Photovoltaic Device by Angela Steinauer, Anna M. Butterfield, Anthony Linden, Agustin Molina-Ontario, David C. Buck, Robert W. Cotta, Luis Echegoyen, Kim K. Baldridge, and Jay S. Siegel on page 1866.
Aldo José Gorgatti Zarbin
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Cengiz Yenikaya; Halil İlkimen; Mehmet Melih Demirel; Burçin Ceyhan; Metin Bülbül; Ekrem Tunca
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Two proton transfer salts and three copper(II) complexes have been synthesized and their antiglaucoma activities were studied in vitro.
Caroline D. Zappielo; Daniel M. Nanicuacua; Walter N. L. dos Santos; Daniel L. F. da Silva; Luiz H. Dall'Antônia; Fernanda M. de Oliveira; Débora N. Clausen; César R. T. Tarley
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Modified carbon black was used as an alternative nano-carbonaceous material for the preconcentration of trace levels of Cd2+ in different samples with posterior determination by flame atomic absorption spectrometry (FAAS).
Roger N. Michels; Elton G. Bonafe; Luana C. Figueiredo; Rúbia M. Suzuki; Lilian D. Tonin; Paula F. Montanher; Alessandro Francisco Martins; Jesui V. Visentainer; Marcelo G. Canteri; Marcelo Augusto A. Silva
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Concentration evaluated of many compounds such as phytosterols, tocopherols, fatty acids and antioxidant, after different applications of fungicides.
Anna M. Hawrył; Agata Ziobro; Ryszard S. Swieboda; Mirosław A. Hawrył; Mykhaylo Chernetskyy; Monika Waksmundzka-Hajnos
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Twelve Cirsium sp. methanolic extracts were analyzed using high-performance liquid chromatography to construct the appropriate fingerprint chromatograms. Obtained chromatograms were compared using various similarity and distance indices and the obtained results were compiled using principal component analysis (PCA).
Ady Giordano; José Vásquez; Mauricio Retamal; Loreto Ascar
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Thin-film extraction procedure used for the determination of selected compounds from water samples.
Letícia Lazzari; Angela L. R. Wagener; Cássia O. Farias; Aída P. Baêta; Cristiane R. Mauad; Alexandre M. Fernandes; Rodolfo Paranhos; Renato S. Carreira
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Organic carbon (OC), N and P daily flow rates from Guanabara Bay to coastal ocean were obtained. Estimated OC, N and P flow rates are regionally and globally significant. Carbon (δ13C) and nitrogen (δ15N) isotopic composition and sterols reveal export of labile carbon, thus, of high nutritive value. The photo was taken during sampling.
Effat Iravani; Sareh Ammari Allahyari; Meisam Torab-Mostaedi
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Efficiency and kinetic of ethylenediaminetetraacetic acid disodium salt (EDTA) degradation showed considerable performance in the presence of phosphate modified nano titania compared to untreated nano titania probably due to better EDTA adsorption.
Rafał Giszter; Marta Fryder; Katarzyna Marcinkowska; Agata Sznajdrowska
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Herbicidal ionic liquids tend to prevent drops from running off the leaf and improve the wettability. Increasing time of contact with the surface of the leaves has a positive influence on the herbicide formulation efficacy.
Mioara Negoiță; Alina Culețu
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Separation, detection, identification and quantification of acrylamide.
Li Yan; Zhu Jing; Ren Lin; Li Yongxin; Zou Xiaoli
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SD-SFO-DLLME (solvent-based demulsification and solidification of a floating organic drop combined with dispersive liquid-liquid microextraction): extractant and dispersing reagent were injected into the sample solution to extract the target compounds for HPLC-UV (high performance liquid chromatography with ultraviolet detection) analysis.
Eraldo L. Lehmann; Deleon N. Correa; Eduardo M. Schmidt; Marcos N. Eberlin; Marco A. Z. Arruda
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This graphical abstract summarizes the dangers of drinking "tape tea" due to the presence of neurotoxic and carcinogenic elements.
Isabelle N. Peixoto; Helivaldo D. S. Souza; Bruno F. Lira; Daniele F. Silva; Edeltrudes O. Lima; José M. Barbosa-Filho; Petrônio F. de Athayde-Filho
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Ten new mesoionic derivatives from the 1,3-thiazolium-5-thiolate system with substituted acetamides were synthesized, had their potential as new drug evaluated in an in silico study and in their activity as antifungal against strains of Candida albicans.
Rahmatollah Rahimi; Maryam Khosravi; Mohammd H. H. Tehrani; Mahboubeh Rabbani; Ebrahim Safavi
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Solid-phase peptide synthesis of dipeptide (histidine-β-alanine) as a chelating agent examined. Trityl chloride resin was used as a carrier.
Anees Ahmad; Luiz F. Silva Júnior
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The oxygen- and nitrogen-substituted indanes were prepared in good yield through iodine(III)-mediated ring contraction of 1,2-dihydronaphthalenes.
Paula A. Oliveira; Rodrigo O. M. A. Souza; Claudio J. A. Mota
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Continuous-flow production of solketal under atmospheric pressure by acid catalyzed ketalization of glycerol.
Camila A. B. Freitas; Antonio S. Silva; Cláudio N. Alves; Walnice M. O. Nascimento; Alessandra S. Lopes; Marcelo O. Lima; Regina C. S. Müller
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The metal contents and physicochemical properties were evaluated in samples of camu-camu from Pará (Amazonia region). The dendrogram shows the separation of 7 genotypes.
Rosanny C. Silva; Marina V. Sarmento; Roselena Faez; Roger J. Mortimer; Adriana S. Ribeiro
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This scheme summarises the spectroelectrochemical results obtained for the samples of the hybrid materials based on polyaniline, chitosan and/or an organically modified clay.
Otávio Augusto Chaves; Breno A. Soares; Maria Aparecida M. Maciel; Carlos Maurício R. Sant'Anna; José Carlos Netto-Ferreira; Dari Cesarin-Sobrinho; Aurélio B. B. Ferreira
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The binding between serum albumin and the bioactive 19-nor-clerodane trans-dehydrocrotonin (t-DCTN) is weak and essentially due to hydrophobic interactions.
Angela Steinauer; Anna M. Butterfield; Anthony Linden; Agustin Molina-Ontario; David C. Buck; Robert W. Cotta; Luis Echegoyen; Kim K. Baldridge; Jay S. Siegel
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The additive substituent effect of phenylmercaptoderivatives of corannulene are investigated by spectroscopic and electrochemical techniques. The per-substituted phenylmercaptocorannulene is incorporated as a replacement for [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) in a photovoltaic device.
Juliana G. A. Silva; Alexander A. Silva; Isabel D. Coutinho; Claudia O. Pessoa; Alberto J. Cavalheiro; Maria G. V. Silva
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Using dereplication, gas chromatography coupled to mass spectrometry (GC-MS) and multivariate analyses by hierarchical cluster analysis (HCA) and partial least squares-discriminant analysis (PLS-DA), of 12 extracts from four Senna spp., hit compounds were identified and the steps of extract fractionation and purification of known compounds were avoided; therefore, in the prospect for new drug prototypes from biological sources, the research approach was improved.
Naeemeh Zari; Jalal Hassan; Kourosh Tabar-Heydar; Seyyed H. Ahmadi
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Green online pre-concentration of rare earth elements REEs and uranium followed by inductively coupled plasma optical emission spectrometry (ICP OES) determination in environmental samples.
Ana Paula Pitarelo; César S. da Fonseca; Luana M. Chiarello; Francisco M. Gírio; Luiz P. Ramos
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Steam explosion with or without dilute phosphoric acid resulted in a good pretreatment performance of cane bagasse. High hydrolysis and fermentation yields were obtained from water-washed steam-treated substrates but the pretreatment water solubles were highly inhibitory. Freeze-drying water-soluble furan compounds and acetic acid to non-inhibitory levels.
Fernando A. S. Vaz; Leandra N. O. Neves; Rafael Marques; Renata T. Sato; Marcone A. L. Oliveira
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Overview of Chromophoreasy: a simple, practical and reliable program that detects and integrates chromatographic and electrophoretic peaks.
Total access: 56860
Dayane A. Santos; Karen P. Lima; Paulo H. Março; Patrícia Valderrama
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A multiproduct calibration based on ultraviolet spectroscopy and Tillman's titration as reference method was developed to predict vitamin C in industrialized juices.
Marcio S. Silva; Daniel Pietrobom
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The saturation transfer difference nuclear magnetic resonance (STD NMR) method was report for lipase-amide interaction as a first-pass design method in the enzymatic kinetic resolution of amines.
Online version ISSN 1678-4790 Printed version ISSN 0103-5053
Journal of the Brazilian Chemical Society
JBCS Editorial and Publishing Office
University of Campinas - UNICAMP
13083-970 Campinas-SP, Brazil
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