JBCS

18:09, Thu Nov 21

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vol. 29, No. 11, 2018, p. 2213-2448

 

Mate extract (Ilex paraguariensis A.St.-Hil.), generally recognized as safe (GRAS by the FDA), was used as broilers feed additive to improve meat quality and shelf-life. Addition of mate extract to broilers feed affects metabolic pathways related to endogenous peptide derived antioxidants in muscle tissue. Chicken meat from broilers supplemented with lower levels of mate extract (250-500 mg per kg of feed) shows increased content of β-alanine, anserine, and carnosine, improving overall quality and oxidative stability of chicken meat. Details are presented in the Article Mate as Dietary Supplement for Broiler Chickens: Effect on the Metabolic Profile and Redox Chemistry of Meat by Caroline Ceribeli, Andressa de Zawadzki, Aline M. C. Racanicci, Luiz A. Colnago, Leif H. Skibsted and Daniel R. Cardoso on page 2266.


Cover Article
J. Braz. Chem. Soc. 2018, 29(11), 2266-2277

Mate as Dietary Supplement for Broiler Chickens: Effect on the Metabolic Profile and Redox Chemistry of Meat

Caroline Ceribeli; Andressa de Zawadzki; Aline M. C. Racanicci; Luiz A. Colnago; Leif H. Skibsted; Daniel R. Cardoso

How to cite this article

Mate extract (Ilex paraguariensis A.St.-Hil.), generally recognized as safe (GRAS by the FDA), was used as broilers feed additive to improve meat quality and shelf-life. Addition of mate extract to broilers feed affects metabolic pathways related to endogenous peptide derived antioxidants in muscle tissue. Chicken meat from broilers supplemented with lower levels of mate extract (250-500 mg per kg of feed) shows increased content of β-alanine, anserine, and carnosine, improving overall quality and oxidative stability of chicken meat. Details are presented in the Article Mate as Dietary Supplement for Broiler Chickens: Effect on the Metabolic Profile and Redox Chemistry of Meat by Caroline Ceribeli, Andressa de Zawadzki, Aline M. C. Racanicci, Luiz A. Colnago, Leif H. Skibsted and Daniel R. Cardoso on page 2266.

https://dx.doi.org/10.21577/0103-5053.20180103

Published online: May 29, 2018
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Communication J. Braz. Chem. Soc. 2018, 29(11), 2213-2219

Old Drawback on Azlactone Formation Revealed by a Combination of Theoretical and Experimental Studies

Pedro P. de Castro; Gabriel M. F. Batista; Danielle L. J. Pinheiro; Hélio F. dos Santos; Giovanni W. Amarante

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Novel insights in the formation of different 2-substituted azlactone heterocycles. The formation of 2-aryl and 2-alkyl azlactones are favored by a sum of both kinetic and thermodynamic factors, while the cyclization of 2-alcoxy azlactones is less favored.

https://dx.doi.org/10.21577/0103-5053.20180155

Published online: August 16, 2018

 

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Articles J. Braz. Chem. Soc. 2018, 29(11), 2220-2232

Air Quality in the Maracana and Deodoro Zones During the Rio 2016 Olympic Games

Carolina A. Bezerra; Nicole J. de Carvalho; Claudio G. P. Geraldino; Cleyton M. da Silva; Graciela Arbilla

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C4-C12 non-oxygenated volatile organic compounds and criteria pollutants were analyzed during the Rio de Janeiro Summer 2016 Olympic Games, in two Olympic zones, Maracana (Tijuca) and Deodoro.

https://dx.doi.org/10.21577/0103-5053.20180099

Published online: May 22, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2233-2243

Effect of Calcination Temperature on Catalytic Performance of CeCu Oxide in Removal of Quinoline by Wet Hydrogen Peroxide Oxidation from Water

Zhaojie Jiao; Guilin Zhou; Haidong Zhang; Yu Shen; Xianming Zhang; Juexuan Li; Xu Gao

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The CeCu-mixed oxide catalyst calcinated at temperature of 650 °C took on the best performance with an oxidation conversion up to 98% for quinoline, a removal efficiency of 80.6% for total organic carbon (TOC) and a low Cu2+ leaching value of 19.3 mg L-1.

https://dx.doi.org/10.21577/0103-5053.20180100

Published online: May 25, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2244-2253

Study of the Naphthenic Corrosion of AISI 316 and AISI 1020 Steels by Light, Scanning Electron and Atomic Force Microscopies (LM, SEM and AFM)

Débora V. Domingos; Fabrício C. Tozzi; Eliane V. Barros; Fernanda E. Pinto; Cristina M. S. Sad; Paulo R. Filgueiras; Valdemar Lacerda Jr.; Heloisa P. Dias; Glória M. V. F. Aquije; Wanderson Romao

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AISI 316 and AISI 1020 steel coupons were analyzed by scanning electron microscopy (SEM) and atomic force microscopy (AFM) before and after immersion in various crude oil samples and their respective blends for 48 days at room temperature.

https://dx.doi.org/10.21577/0103-5053.20180101

Published online: May 25, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2254-2265

Development, Optimization and Validation of a GC Method by Polarity Phase Constants and Statistical Design of Experiments for the Determination of Monoterpenes in Alpinia zerumbet Essential Oil

Igor C. Cardoso; Marcos J. Nakamura; Virginia G. Correia; Henrique M. G. Pereira; Maria D. Behrens; Marcelo R. R. Tappin

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In this report, we described the optimization by response surface methodology of a new analytical method by gas chromatography (GC) for analysis of Alpinia zerumbet essential oil.

https://dx.doi.org/10.21577/0103-5053.20180102

Published online: May 29, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2266-2277

Mate as Dietary Supplement for Broiler Chickens: Effect on the Metabolic Profile and Redox Chemistry of Meat

Caroline Ceribeli; Andressa de Zawadzki; Aline M. C. Racanicci; Luiz A. Colnago; Leif H. Skibsted; Daniel R. Cardoso

How to cite this article

 

Mate extract in animal diet improves the redox status of meat by changing its metabolic profile towards the production of endogenous antioxidants.

https://dx.doi.org/10.21577/0103-5053.20180103

Published online: May 29, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2278-2286

Exponential Fed-Batch Cultures of Klebsiella pneumoniae under Anaerobiosis Using Raw Glycerol as a Substrate to Obtain Value-Added Bioproducts

Allan Morcelli; Rosane Rech; Andre Klafke; Rafael Pelegrini; Marco A. Z. Ayub

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Residual glycerol can be used as substrate in the production of valuable compounds by Klebsiella pneumonia in exponentially fed-batch cultures (EFBC).

https://dx.doi.org/10.21577/0103-5053.20180104

Published online: May 29, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2287-2298

Wastewater-Based Epidemiology of Cocaine in the Brazilian Federal District: Spatial Distribution, Weekly Variation and Sample Preservation Strategies

Fernando F. Sodré; Rafael S. Feitosa; Wilson F. Jardim; Adriano O. Maldaner

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Cocaine use in the Brazilian Federal District, assessed by wastewater-based epidemiology (WBE), revealed higher consumption in the north area, notably during weekends. A nationwide survey may be carried out with sewage samples adjusted to pH 2 and transported within three days under ambient conditions.

https://dx.doi.org/10.21577/0103-5053.20180105

Published online: May 29, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2299-2307

Occurrence of Pesticides in Pericarpium Citri Reticulatae and Related Products Using Syringe Filter-Based Cleanup

Fuxin Liu; Xiaowen Dou; Jiaoyang Luo; Dandan Kong; Zhuowen Fan; Meihua Yang

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Persistent organochlorines were found in commercial Pericarpium Citri Reticulatae by a "push-and-pull" needle filter based cleanup and gas chromatography (GC) analysis.

https://dx.doi.org/10.21577/0103-5053.20180107

Published online: June 4, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2308-2325

Synthesis, Characterization and Evaluation of in vitro Antitumor Activities of Novel Chalcone-Quinolinone Hybrid Compounds

Giulio D. C. d'Oliveira; Andrea F. Moura; Manoel O. de Moraes; Caridad N. Perez; Luciano M. Liao

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Chalcone-quinolinone synthesis: one step reaction, good yield and pure precipitate.

https://dx.doi.org/10.21577/0103-5053.20180108

Published online: June 4, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2326-2333

Automatic Procedure to Determine Acidity in Fuel Ethanol by Photometric Titration Using Binary Search and Multicommuted Flow Analysis

Manoel J. A. Lima; Boaventura F. Reis

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A pictorial overview of the titration procedures for ethanol fuel employing manual and automatic approaches.

https://dx.doi.org/10.21577/0103-5053.20180109

Published online: June 8, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2334-2341

In-Line Incomplete Solid-Liquid Extraction for Spectrophotometric Determination of Soluble Inorganic Phosphorus in Plants and Foods

Caio C. V. Macedo; Rodrigo S. N. Mancini; Carolina Y. Arakaki; Diogo L. Rocha

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Incomplete and reproducible soluble inorganic phosphorus extraction from vegetable materials and foods prior to spectrochemical analysis in a flow injection analysis (FIA) system with zones penetration.

https://dx.doi.org/10.21577/0103-5053.20180110

Published online: June 8, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2342-2349

N-Alkylated Sulfamic Acid Derivatives as Organocatalyst in Multicomponent Synthesis of Fatty Dihydropyrimidinones

Carolina R. L. Hack; Larissa Porciuncula; Andressa C. H. Weber; Caroline R. M. D'Oca; Dennis Russowsky; Jaqueline M. Moura; Luiz A. A. Pinto; Marcelo G. M. D'Oca

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N-Alkylated sulfamic acid derivatives are introduced as promising acidic organocatalysts in multicomponent reactions to the synthesis of dihydropyrimidinones.

https://dx.doi.org/10.21577/0103-5053.20180112

Published online: June 11, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2350-2362

Geometry and Stability of Molecular Clusters: Factor to Be Considered in Biomolecular Activity

Noam G. da Silva; Alexandre M. Alecrim; Renyer A. Costa; Kelson M. T. de Oliveira

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Molecular clusters are proposed as explanation for the different activities of betulinic and melaleucic acids, compounds with very similar properties.

https://dx.doi.org/10.21577/0103-5053.20180113

Published online: June 12, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2363-2377

Compound-Specific δ13C of n-Alkanes: Clean-Up Methods Appraisal and Application to Recent Sediments of a Highly Contaminated Bay

Milena Ceccopieri; Arthur L. Scofield; Lilian Almeida; Angela L. R. Wagener

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The image summarizes the δ13C equation and the isotopic signature from different carbon sources in the Guanabara Bay, i.e., phytoplankton, mangrove trees, fossil fuel from boat traffic and industries.

https://dx.doi.org/10.21577/0103-5053.20180114

Published online: June 14, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2378-2386

Al-MCM-41 Synthesized from Kaolin via Hydrothermal Route: Structural Characterization and Use as an Efficient Adsorbent of Methylene Blue

Evânia C. Santos; Luelc S. Costa; Edipo S. Oliveira; Raquel A. Bessa; Armando D. L. Freitas; Cristiane P. Oliveira; Ronaldo F. Nascimento; Adonay R. Loiola

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Natural kaolin is efficiently converted, via dealumination and hydrothermal route, to Al-Mobil Composition of Matter No. 41 (Al-MCM-41) mesoporous materials, with a high area surface, showing high performance on methylene blue adsorption from aqueous medium.

https://dx.doi.org/10.21577/0103-5053.20180115

Published online: June 18, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2387-2396

Oxidation of Single-Walled Carbon Nanotubes under Controlled Chemical Conditions

Arthur B. Porto; Glaura G. Silva; Hélio F. dos Santos; Luiz F. C. de Oliveira

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Single-walled carbon nanotubes (SWCNT) are oxidized in acid medium under controlled NO2+ concentration and reaction time.

https://dx.doi.org/10.21577/0103-5053.20180116

Published online: June 18, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2397-2404

Preparation of Microcapsules of Slow-Release NPK Compound Fertilizer and the Release Characteristics

Wancheng Pang; Dejia Hou; Huan Wang; Shu Sai; Baorui Wang; Jingwen Ke; Gaobing Wu; Qing Li; Mark T. Holtzapple

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The graphical abstract is an amplified structure of slow-release fertilizer. Microcapsule structure has disappeared after water soaking and the nutrient is slowly released completely.

https://dx.doi.org/10.21577/0103-5053.20180117

Published online: June 19, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2405-2416

Synthesis and Antibacterial Evaluation of 3,5-Diaryl-1,2,4‑oxadiazole Derivatives

Felipe S. Cunha; Joseli M. R. Nogueira; Alcino P. de Aguiar

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Twenty 1,2,4-oxadiazole derivatives were synthesized and evaluated against five different bacteria.

https://dx.doi.org/10.21577/0103-5053.20180118

Published online: June 20, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2417-2425

Use of a Natural Sorbent as Alternative Solid-Phase Microextraction Coating for the Determination of Polycyclic Aromatic Hydrocarbons in Water Samples by Gas Chromatography-Mass Spectrometry

Natália G. Suterio; Sângela N. do Carmo; Dilma Budziak; Josias Merib; Eduardo Carasek

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In this study, the use of a biosorbent-based coating in solid-phase microextraction was proposed for the determination of polycyclic aromatic hydrocarbons in water samples.

https://dx.doi.org/10.21577/0103-5053.20180119

Published online: June 22, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2426-2440

Chemometric-Assisted Hydrophilic Interaction Chromatographic Method for the Determination of Gadolinium-Based Magnetic Resonance Imaging Contrast Agent in Liposomes

Ana Luiza C. Maia; Pedro Henrique R. da Silva; Christian Fernandes; Aline T. M. e Silva; André Luís B. de Barros; Daniel Crístian F. Soares; Gilson A. Ramaldes

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Development, using chemometrics tools, of a hydrophilic interaction chromatographic method for the determination of gadodiamide in liposomes.

https://dx.doi.org/10.21577/0103-5053.20180120

Published online: June 22, 2018

 

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J. Braz. Chem. Soc. 2018, 29(11), 2441-2448

Simultaneous Determination of Four Antibiotics in Raw Milk by UPLC-MS/MS Using Protein Precipitation as Sample Preparation: Development, Validation, and Application in Real Samples

Thiago Magon; Roberta da Silveira; Marília B. Galuch; Eder Paulo Fagan; Ana Flavia D. Feitoza; Sylvio V. Palombini; Oscar O. Santos; Jesui V. Visentainer

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Determination of tetracycline, oxytetracycline, penicillin G and ceftiofur in raw milk by ultra-performance liquid chromatography tandem mass spectrometry (UPLC-MS/MS) using protein precipitation as sample preparation: development, validation, and application in raw milk samples from dairy cows medicated with tetracycline (24, 48, 72 and 96 h after treatment) for subclinical mastitis.

https://dx.doi.org/10.21577/0103-5053.20180121

Published online: June 25, 2018

 

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Online version ISSN 1678-4790 Printed version ISSN 0103-5053
Journal of the Brazilian Chemical Society
JBCS Editorial and Publishing Office
University of Campinas - UNICAMP
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