JBCS

15:18, Thu Nov 21

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vol. 31, No. 4, 2020, p. 627-855

 

The 3D-printed scaffold can upconvert NIR laser irradiation into visible light. Higher transparency of biological tissues at NIR wavelengths enables delivering visible light to deep-layers to locally activate a photosensitizer drug (erythrosine B), which in turns generates reactive oxygen species (ROS) involved in tumor cell destruction. The scaffold, a combination of organic (polycaprolactone) and inorganic (apatite) compounds, is suitable for bone repair and photodynamic therapy. Details are presented in the Article Upconversion 3D Printed Composite with Multifunctional Applications for Tissue Engineering and Photodynamic Therapy by Karina Nigoghossian, Sybele Saska, Livia M. Christovam, Fernanda Coelho, Cesar Augusto G. Beatrice, Alessandra A. Lucas, Paulo I. Neto, Jorge Vicente L. da Silva, Agnieszka Tercjak, Maurício S. Baptista, Luiz Henrique Catalani, Raquel M. Scarel-Caminaga, Ticiana S. O. Capote and Sidney José L. Ribeiro on page 638.


Cover Article
J. Braz. Chem. Soc. 2020, 31(4), 638-652

Upconversion 3D Printed Composite with Multifunctional Applications for Tissue Engineering and Photodynamic Therapy

Karina Nigoghossian ; Sybele Saska; Livia M. Christovam; Fernanda Coelho; Cesar Augusto G. Beatrice; Alessandra A. Lucas; Paulo I. Neto; Jorge Vicente L. da Silva; Agnieszka Tercjak ; Maurício S. Baptista; Luiz Henrique Catalani; Raquel M. Scarel-Caminaga; Ticiana S. O. Capote; Sidney José L. Ribeiro

How to cite this article

The 3D-printed scaffold can upconvert NIR laser irradiation into visible light. Higher transparency of biological tissues at NIR wavelengths enables delivering visible light to deep-layers to locally activate a photosensitizer drug (erythrosine B), which in turns generates reactive oxygen species (ROS) involved in tumor cell destruction. The scaffold, a combination of organic (polycaprolactone) and inorganic (apatite) compounds, is suitable for bone repair and photodynamic therapy. Details are presented in the Article Upconversion 3D Printed Composite with Multifunctional Applications for Tissue Engineering and Photodynamic Therapy by Karina Nigoghossian, Sybele Saska, Livia M. Christovam, Fernanda Coelho, Cesar Augusto G. Beatrice, Alessandra A. Lucas, Paulo I. Neto, Jorge Vicente L. da Silva, Agnieszka Tercjak, Maurício S. Baptista, Luiz Henrique Catalani, Raquel M. Scarel-Caminaga, Ticiana S. O. Capote and Sidney José L. Ribeiro on page 638.

https://dx.doi.org/10.21577/0103-5053.20190228

Published online: September 23, 2019
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Articles J. Braz. Chem. Soc. 2020, 31(4), 627-637

Study of the Effect of Inhibitors Solutions on the Chemical Composition of Waxes by Rheology Tests and High Resolution Mass Spectrometry

Lindamara M. Souza; Samantha R. C. Silva; Paulo R. Filgueiras; Francine D. dos Santos; Géssica A. Vasconcelos;
Valdemar Lacerda Jr. ; Boniek G. Vaz; Wanderson Romão

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Four oils were treated with five inhibitors solutions and evaluated by rheology. These oils were fractionated by the SAP method (saturated, aromatic and polar) and the saturated fraction was analyzed by high resolution mass spectrometry (atmospheric pressure chemical ionization using a positive ionization mode (APCI(+)) Orbitrap) and two-dimensional gas chromatography coupled to quadrupole mass spectrometry (GC x GC-qMS).

https://dx.doi.org/10.21577/0103-5053.20190221

Published online: September 17, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 638-652

Upconversion 3D Printed Composite with Multifunctional Applications for Tissue Engineering and Photodynamic Therapy

Karina Nigoghossian ; Sybele Saska; Livia M. Christovam; Fernanda Coelho; Cesar Augusto G. Beatrice; Alessandra A. Lucas; Paulo I. Neto; Jorge Vicente L. da Silva; Agnieszka Tercjak ; Maurício S. Baptista; Luiz Henrique Catalani; Raquel M. Scarel-Caminaga; Ticiana S. O. Capote; Sidney José L. Ribeiro

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Erythrosine photosensitizer (PS)-containing polycaprolactone (PCL)/upconversion nanoparticles (UCNPs)-apatite composite for biomedical applications in the therapy-stimulated bone repair and photodynamic therapy (PDT).

https://dx.doi.org/10.21577/0103-5053.20190228

Published online: September 23, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 653-661

Potential Slow Release Fertilizers Based on K2MgSiO4 Obtained from Serpentinite

Fabiane C. Ballotin; Wedisson O. Santos; Edson M. Mattiello; Ottávio Carmignano; Ana Paula C. Teixeira; Rochel M. Lago

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K2MgSiO4 was produced by impregnation of serpentinite rock with KOH and thermal treatment. New materials released K in a slow rate than KCl, showing potential as slow release K-fertilizers.

https://dx.doi.org/10.21577/0103-5053.20190229

Published online: September 25, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 662-672

A Protocol for Fish Lipid Analysis Using Nuclear Magnetic Resonance Spectroscopy

Natalia Cristina Mor; Banny S. B. Correia; Adalberto Luis Val; Ljubica Tasic

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An easy-to-follow methodology for fish lipids analysis by nuclear magnetic resonance (NMR) spectroscopy is presented. Biological sample collection, sample preparation, lipid extraction, NMR spectroscopy analysis, statistical data analysis and the care needed in each step execution are explained in detail.

https://dx.doi.org/10.21577/0103-5053.20190230

Published online: September 26, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 673-682

Geochemical Investigation of Tar Balls Collected in a Brazilian Beach Using Biomarkers, Ni/V, δ13C Ratios and Ultra-High Resolution FT‑ICR Mass Spectrometry

Bárbara D. Lima; Laercio L. Martins; Lívia C. Santos; Eliane S. de Souza; Marcos A. Pudenzi; Heliara L. Nascimento; Marcos N. Eberlin; Georgiana F. da Cruz

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Geochemical investigation of tar balls collected in two distinct years (2012 and 2014) in a Brazilian beach using several analytical techniques suggesting that the area is subjected to frequent spill from the same source.

https://dx.doi.org/10.21577/0103-5053.20190231

Published online: September 26, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 683-693

Spatial and Temporal Effects of Decommissioning a Zinc Smelter on the Sediment Quality of an Estuary System: Sepetiba Bay, Rio de Janeiro, Brazil

Rodrigo A. Gonçalves; Douglas F. Oliveira; Carlos Eduardo Rezende; Phelipe Almeida; Luiz D. de Lacerda; Bernardo A. P. da Gama; José Marcus Godoy

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Environmental actions, related to the Ingá Mercantil legacy, led to a Zn reduction in surface sediments.

https://dx.doi.org/10.21577/0103-5053.20190232

Published online: September 27, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 694-702

Near-Infrared Luminescence from Visible-Light-Sensitized Ruthenium(II)‑Neodymium(III) Heterobimetallic Bridged Complexes Containing Alkoxy(silyl) Functional Groups

Rafael M. Sábio ; Silvia H. Santagneli; Marie Gressier; José M. A. Caiut; Wallance M. Pazin; Robson R. Silva; Sidney J. L. Ribeiro; Marie-Joëlle Menu

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The successful fabrication of two silylated ruthenium(II)-neodymium(III) heterobimetallic complexes with excellent photophysical properties allow grafting onto any silicated matrix suggesting their application as new luminescent near infrared (NIR)-emitting biolabels.

https://dx.doi.org/10.21577/0103-5053.20190233

Published online: October 1, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 703-715

New Allyldithiocarbimates: Synthesis, Structure and Antifungal Activity against Phakopsora pachyrhizi and Hemileia vastatrix

Antonio E. C. Vidigal; Mayura M. M. Rubinger; Lucas F. da Silva; Laércio Zambolim; Arthur B. D. Pereira; Silvana Guilardi; Rafael A. C. Souza; Javier Ellena

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New tetraphenylphosphonium (Z)-allyldithiocarbimates synthesized inhibit the germination of phytopathogenic fungi.

https://dx.doi.org/10.21577/0103-5053.20190234

Published online: October 3, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 716-723

Chemometric Optimization of the Methodology for Determination of Molybdenum in Soils and Plants by Square Wave Adsorptive Stripping Voltammetry

José Ricardo de Carvalho; Efraim Lázaro Reis ; César Reis; Odilaine I. C. Damasceno; Antônio Augusto Neves ; Alexsandro Antônio Matias

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A voltammetric method was developed based on the adsorption of the complex of molybdenum(VI) with 8-hydroxyquinoline, using square wave cathodic stripping voltammetry. The concentration of the support electrolyte, frequency, amplitude and deposition time were optimized by factorial design in relation to the reduction of molybdenum(VI) current. The results obtained for the determination of MoVI in soils and leaves of vegetables show good agreement.

https://dx.doi.org/10.21577/0103-5053.20190235

Published online: October 3, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 724-730

Metabolization of Insecticidal Amides from Leaves of Piper tuberculatum by Heraclydes hectorides and Naupactus bipes

Clécio S. Ramos ; Marcílio W. F. Silva; Marcilio M. Moraes; Argus V. Almeida; Sérgio A. Vanin; Massuo J. Kato

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The amides from leaves of Piper tuberculatum are hydrolyzed by the weevil N. bipes and by caterpillars of H. hectorides but not bygeneralist grasshoppers.

https://dx.doi.org/10.21577/0103-5053.20190236

Published online: October 7, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 731-738

The Comparative Investigation of Corrosion and Passivation for X65 Carbon Steel in pH 1 to 5 HNO3 Solutions without and with 0.01 mol L-1 NaNO2

Rongjiao Deng; Pei Zhang; Xiaoying Zhao; Guanyu Cai; Hui Liu; Jinping Xiong ; Yong Zhou

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With the addition of 0.01 mol L-1 NaNO2 in pH 1 to 5 HNO3 solutions, the electrochemical behavior of X65 carbon steel transferred from the activation in the solutions free of NaNO2 to the passivation in the solutions containing NaNO2.

https://dx.doi.org/10.21577/0103-5053.20190237

Published online: October 7, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 739-745

Fast and Ecological Liquid-Liquid Separation Method for Preparing Quinones Enriched Extract from Nigella sativa Oil

Klara Urbanova; Pavel Kloucek; Jaroslav Havlik; Irena Valterova; Ladislav Kokoska

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A fast, inexpensive, and ecological method for preparation of extract with high content of Nigella sativa quinones.

https://dx.doi.org/10.21577/0103-5053.20190238

Published online: October 8, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 746-755

Ultrasound-Promoted Synthesis, Structural Characterization and in vitro Antimicrobial Activity of New
5-Aryl-3-(2-hydroxyphenyl)-4,5-dihydro-1H-pyrazole-1-carboximidamides

Danilo Y. de Albuquerque; Andressa C. Damim; Eliandro Faoro; Gleison A. Casagrande; Davi F. Back; Sidnei Moura; Claudio M. P. de Pereira; Kelly M. P. de Oliveira; Lucas Pizzuti

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Thirteen new amidino pyrazolines were synthesized under ultrasound in 15-83% yield. Some examples showed promising antibacterial activity.

https://dx.doi.org/10.21577/0103-5053.20190239

Published online: October 8, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 756-767

Residue-Based CaO Heterogeneous Catalysts from Crab and Mollusk Shells for FAME Production Via Transesterification

Claudia Cristina Cardoso ; Alexsandro S. Cavalcanti; Ricardo O. Silva; Severino Alves Junior; Fabiana P. de Sousa; Vânya Marcia D. Pasa; Santiago Arias; Jose G. A. Pacheco

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Different species of fishery residues present excellent catalytic activities in the synthesis of biodiesel and can represent a technological-socio-environmental solution for the coastal community of the Northeastern of Brazil.

https://dx.doi.org/10.21577/0103-5053.20190240

Published online: October 8, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 768-774

Ab Initio Study of 17α-Ethinylestradiol and Estrone Molecules Interacting with Single Wall Carbon Nanotube

Shuanne M. Castro; Herisson C. Ribeiro; Adriana B. Araújo; Silvete Guerini

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Band structure and local density of states (LDOS), around the Fermi level, for (8.0) single wall carbon nanotube (SWCNT) plus ethinylestradiol molecule and estrone molecule, in most stable configurations.

https://dx.doi.org/10.21577/0103-5053.20190241

Published online: October 10, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 775-787

Metabolomics-Based Discovery of Biomarkers with Cytotoxic Potential in Extracts of Myracrodruon urundeuva

Caio B. Castro; Licia R. Luz; Jhonyson A. C. Guedes ; Diogo D. Porto; Maria Francilene S. Silva; Gisele S. Silva; Paulo R. V. Ribeiro; Kirley M. Canuto ; Edy S. Brito ; Dávila S. Zampieri; Claúdia Ó. Pessoa; Guilherme J. Zocolo

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Chemical identification and determination of the biomarkers associated with the cytotoxic potential of extracts.

https://dx.doi.org/10.21577/0103-5053.20190242

Published online: October 10, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 788-802

Study of Thermoplastic Extrusion and Its Impact on the Chemical and Nutritional Characteristics and Two Sorghum Genotypes SC 319 and BRS 332

Flávia A. Campelo; Gilberto S. Henriques; Maria Lucia F. Simeone ; Valéria A. V. Queiroz; Mauro R. Silva; Rodinei Augusti ; Júlio O. F. Melo ; Inayara C. A. Lacerda; Raquel L. B. Araújo

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Evaluation of the effect of extrusion on the discrimination of Sorghum bicolor by paper spray mass spectrometry.

https://dx.doi.org/10.21577/0103-5053.20190243

Published online: October 14, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 803-812

Chitosan-Sodium Alginate Polyelectrolyte Complex Coating Pluronic® F127 Nanoparticles Loaded with Citronella Essential Oil

Mariele P. Sanches; Idejan P. Gross; Rodrigo H. Saatkamp; Alexandre L. Parize; Valdir Soldi

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The present study reports the high encapsulation efficiency and the in vitro release study of citronella essential oil in Pluronic® F127 nanoparticles coated with chitosan-sodium alginate polyelectrolyte complex.

https://dx.doi.org/10.21577/0103-5053.20190244

Published online: October 14, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 813-820

Insecticidal and Acaricidal Activity of Essential Oils Rich in (E)-Nerolidol from Melaleuca leucadendra Occurring in the State of Pernambuco (Brazil) and Effects on Two Important Agricultural Pests

Milena M. C. da Silva; Claudio A. G. da Camara; Marcilio M. de Moraes; João P. R. de Melo; Rodrigo B. dos Santos; Roberta C. S. Neves

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Essential oils rich in (E)-nerolidol were identified in different parts of M. leucadendra from Pernambuco, Brazil. Essential oils presented high toxicity against adults and eggs of T. urticae and P. xylostella

https://dx.doi.org/10.21577/0103-5053.20190245

Published online: October 15, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 821-832

Synthesis of Glycerol-Derived 4-Alkyl-Substituted 1,2,3-Triazoles and Evaluation of Their Fungicidal, Phytotoxic, and Antiproliferative Activities

Adilson V. Costa ; Luiza C. Moreira; Roberta T. Pinto; Thammyres A. Alves; Vitor V. Schwan; Vagner T. de Queiroz; Milene M. Praça-Fontes ; Róbson Ricardo Teixeira ; Pedro A. B. Morais; Waldir C. de Jesus Júnior

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Nine 1,2,3-triazole derivatives were synthesized and had their fungicidal, phytotoxic and antiproliferative activities evaluated.

https://dx.doi.org/10.21577/0103-5053.20190246

Published online: October 16, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 833-848

Structural and Functional Stabilization of Sericin from Bombyx mori Cocoons in a Biopolysaccharide Film: Bioorigami for Skin Regeneration

Victor M. Balcão; Liliam K. Harada; Ludmilla R. Jorge; José M. Oliveira Jr.; Matthieu Tubino; Marta M. D. C. Vila

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Sericin extracted from Bombyx mori cocoons was used for the development of a film for use in human skin.

https://dx.doi.org/10.21577/0103-5053.20190247

Published online: October 21, 2019

 

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J. Braz. Chem. Soc. 2020, 31(4), 849-855

Isolation, in vitro and in silico Evaluation of Phenylethanoid Glycoside from Arrabidaea brachypoda as Lipoxygenase Inhibitor

Camila S. Bertanha; Valéria M. M. Gimenez; Ricardo A. Furtado; Denise C. Tavares; Wilson R. Cunha; Márcio L. A. e Silva ; Ana H. Januario ; Alexandre Borges; Daniel F. Kawano; Renato L. T. Parreira ; Patrícia M. Pauletti

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Obtention of conandroside as a promising lipoxygenase inhibitor in an in vitro assay and molecular docking analysis.

https://dx.doi.org/10.21577/0103-5053.20190248

Published online: October 22, 2019

 

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Online version ISSN 1678-4790 Printed version ISSN 0103-5053
Journal of the Brazilian Chemical Society
JBCS Editorial and Publishing Office
University of Campinas - UNICAMP
13083-970 Campinas-SP, Brazil

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