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vol. 31, No. 5, 2020, p. 857-1092

 

Novel 3-aminofurostane alkaloids were characterized from Solanum paniculatum roots. Two compounds were identified as new natural compounds: (25R)-3β-amino-furost-5-en-22α,26-diol O(26)-β-D-glucopyranoside (fatimagraine) and (25R)-3β-amino-furost-22-en, 26-ol O(26)-β-D-glucopyranoside (bhattacharyyaine). Details are presented in the Article 3-Aminofurostane Alkaloids from Solanum paniculatum (“Jurubeba Verdadeira”) Roots by Tania M. S. Silva, Telma M. G. Silva, Maria F. Agra and Celso A. Camara on page 1030.


Cover Article
J. Braz. Chem. Soc. 2020, 31(5), 1030-1042

3-Aminofurostane Alkaloids from Solanum paniculatum ("Jurubeba Verdadeira") Roots

Tania M. S. Silva; Telma M. G. Silva; Maria F. Agra; Celso A. Camara

How to cite this article

Novel 3-aminofurostane alkaloids were characterized from Solanum paniculatum roots. Two compounds were identified as new natural compounds: (25R)-3β-amino-furost-5-en-22α,26-diol O(26)-β-D-glucopyranoside (fatimagraine) and (25R)-3β-amino-furost-22-en, 26-ol O(26)-β-D-glucopyranoside (bhattacharyyaine). Details are presented in the Article 3-Aminofurostane Alkaloids from Solanum paniculatum ("Jurubeba Verdadeira") Roots by Tania M. S. Silva, Telma M. G. Silva, Maria F. Agra and Celso A. Camara on page 1030.

https://dx.doi.org/10.21577/0103-5053.20190269

Published online: December 10, 2019
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Communication J. Braz. Chem. Soc. 2020, 31(5), 857-866

An Expedient Synthesis of Tacrine-Squaric Hybrids as Potent, Selective and Dual‑Binding Cholinesterase Inhibitors

Marco A. Ceschi ; Renan M. Pilotti; João P. B. Lopes; Henrique Dapont; João B. T. da Rocha; Blessing A. Afolabi ; Isabella A. Guedes; Laurent E. Dardenne

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Tacrine-squaric hybrids were synthesized through a simple synthetic methodology from squaric acid in good yields (80-99%). All compounds were strongly selective to acetylcholinesterase (AChE) and were able to bind at both catalytic active site (CAS) and peripheral anionic site (PAS) in the active site of the enzyme.

https://dx.doi.org/10.21577/0103-5053.20200019

Published online: February 4, 2020

 

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Articles J. Braz. Chem. Soc. 2020, 31(5), 867-885

Crystal Structure and 1H NMR Experimental and Theoretical Study of Conformers of 5-Methyl-1-(4'-methylphenylsulfonylamino)-1H-[1,2,3]-triazole-4-carboxylic Acid Ethyl Ester and 5-Methyl-1-(phenylsulfonylamino)-1H-[1,2,3]-triazole-4-carboxylic Acid Ethyl Ester

Maria C. R. Freitas ; Vinicius R. Campos; Jackson A. L. C. Resende; Marcos M. P. da Silva; Vitor F. Ferreira; Anna Claudia Cunha; José W. M. Carneiro; Mateus R. Lage; Leonardo A. de Souza; Haroldo C. Silva; Wagner B. de Almeida

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Experimental and density functional theory (DFT) simulated evidences of conformational change of 1,2,3-triazole from solid form to CDCl3 solution.

https://dx.doi.org/10.21577/0103-5053.20190249

Published online: October 23, 2019

 

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Crystal Data 1 (CIF)
Crystal Data 2 (CIF)

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J. Braz. Chem. Soc. 2020, 31(5), 886-893

Assessment of Reaction Parameters in the Polymeric Carbon Nitride Thermal Synthesis and the Influence in Photocatalytic Hydrogen Production

Dalila S. Monteiro; Marcus Vinicius S. Silva; Luciana A. Silva

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Thiourea thermally treated for longer time with intermediary heating rate gave rise to the most active photocatalyst for hydrogen production, S-doped polymeric carbon nitride (PCN).

https://dx.doi.org/10.21577/0103-5053.20190251

Published online: October 29, 2019

 

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J. Braz. Chem. Soc. 2020, 31(5), 894-903

Simple GFAAS Method for Determination of Pb, As, and Cd in Cannabidiol Extracts Used for Therapeutic Purposes

Patricia A. Nascimento; Juliana Schultz; Mario H. Gonzalez; Andrea Oliveira

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There is increasing permitted use worldwide of cannabidiol (CBD) extracts for medical purposes, such as the treatment of epilepsy and other chronic diseases. It is therefore necessary to be able to determine the inorganic chemical compositions of these formulations.

https://dx.doi.org/10.21577/0103-5053.20190252

Published online: October 29, 2019

 

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J. Braz. Chem. Soc. 2020, 31(5), 904-915

Optimization of Alkaline, Acidic, Ionic Liquid and Oxidative Pretreatments for Coconut Waste Conversion into Fermentable Sugars

Magale K. D. Rambo ; Polyana M. de Melo ; Márcia M. C. Ferreira; Michele C. D. Rambo; Daniel A. Bertuol; Victor L. Mota

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Four different pretreatments were optimized and tested in coconut waste, to evaluate its potential as source of fermentable sugars.

https://dx.doi.org/10.21577/0103-5053.20190254

Published online: October 31, 2019

 

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J. Braz. Chem. Soc. 2020, 31(5), 916-926

Methodology Development and Validation of Amphotericin B Stability by HPLC‑DAD

Marciela B. Montenegro; Stefânia P. de Souza; Raquel A. C. Leão; Helvécio V. A. Rocha; Claudia M. de Rezende; Rodrigo O. M. A. de Souza

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This is amphotericin B (AMB), an antibiotic highly unstable. For this reason, the objective of this work is the development of an indicative method of stability for AMB.

https://dx.doi.org/10.21577/0103-5053.20190256

Published online: November 7, 2019

 

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J. Braz. Chem. Soc. 2020, 31(5), 927-940

In silico Risk Assessment Studies of New Psychoactive Substances Derived from Amphetamines and Cathinones

Eduardo B. de Melo ; João P. A. Martins ; Caio H. P. Rodrigues ; Aline T. Bruni

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This paper aims to create a program using Java programming language for-log of half maximal inhibitory concentration (pIC50) prediction of amphetamines and cathinones using the fundamentals of quantitative structure-activity relationship (QSAR).

https://dx.doi.org/10.21577/0103-5053.20190258

Published online: November 13, 2019

 

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J. Braz. Chem. Soc. 2020, 31(5), 941-952

Chemically-Activated Biochar from Ricinus communis L. Cake and Their Potential Applications for the Voltammetric Assessment of Some Relevant Environmental Pollutants

Cristiane Kalinke; Paulo R. de Oliveira; Antonio S. Mangrich ; Luiz H. Marcolino‑Junior; Márcio F. Bergamini

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Castor bean activated biochar was characterized and used for electrodes construction for voltammetric application.

https://dx.doi.org/10.21577/0103-5053.20190259

Published online: November 19, 2019

 

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Total access: 1391


J. Braz. Chem. Soc. 2020, 31(5), 953-962

Synthesis, in silico Study and Antimicrobial Evaluation of New Diesters Derived from Phthaloylglycine

Rafael F. de Oliveira ; Helivaldo D. S. Souza; Francinara S. Alves; Abraão P. de Sousa; Priscila S. V. de Lima; Min-Fu N. Huang; Laísa V. Cordeiro; Hermes Diniz Neto ; Edeltrudes O. Lima; Emmely O. Trindade; José M. Barbosa-Filho ; Petrônio F. de Athayde‑Filho

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New diesters compounds derived from phthaloylglycine and their use in medicinal chemistry are still unpublished. Due to the increase in antimicrobial resistance, new categories of substances with potential biological activity against pathogenic microorganisms have been increasingly studied.

https://dx.doi.org/10.21577/0103-5053.20190260

Published online: November 19, 2019

 

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J. Braz. Chem. Soc. 2020, 31(5), 963-970

An Alternative Spectrophotometric Determination of Carbaryl Insecticide Residues in Water Samples Using the Cerium-Catalyzed Belousov-Zhabotinsky Oscillating Reaction

Titikan Somboon ; Yanawath Santaladchaiyakit; Sira Sansuk; Supalax Srijaranai

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Spectrophotometric determination of carbaryl using the cerium-catalyzed Belousov-Zhabotinsky reaction.

https://dx.doi.org/10.21577/0103-5053.20190261

Published online: November 19, 2019

 

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Total access: 966


J. Braz. Chem. Soc. 2020, 31(5), 971-981

Zn2Al Layered Double Hydroxides Intercalated with Nitrate and p-Aminobenzoate as Ultraviolet Protective Agents in Low-Density Polyethylene Nanocomposites and Natural Insulating Oils

Neffer A. G. Gómez; Gabriel M. Silva; Helena M. Wilhelm; Fernando Wypych

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Zn2Al layered double hydroxides were used as ultraviolet oxidation protectors in low density polyethylene and natural insulating oils.

https://dx.doi.org/10.21577/0103-5053.20190262

Published online: November 21, 2019

 

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J. Braz. Chem. Soc. 2020, 31(5), 982-989

Specific Disulfide Bond Formation Directed by Peptide Nucleic Acids

Lin Cai; Wen Hou

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Peptides were linked to the pair of complementary peptide nucleic acid (PNAs) by native chemical ligation, respectively, and base pairing drove the two peptides into close proximity for interchain disulfide bond formation.

https://dx.doi.org/10.21577/0103-5053.20190263

Published online: November 22, 2019

 

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J. Braz. Chem. Soc. 2020, 31(5), 990-998

Chitosan and Agaricus brasiliensis Polysaccharides Films: A Preliminary Study

Maria L. C. Gonzaga; Matheus S. Campelo; Katarina B. Saraiva; Alan Q. S. Santos; Luzia K. A. M. Leal; Nágila M. P. S. Ricardo; Sandra A. Soares; Maria Elenir N. P. Ribeiro

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Polysaccharide films of Agaricus brasiliensis mushroom for wound care.

https://dx.doi.org/10.21577/0103-5053.20190264

Published online: November 25, 2019

 

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J. Braz. Chem. Soc. 2020, 31(5), 999-1010

Combretastatin A-4: The Antitubulin Agent that Inspired the Design and Synthesis of Styrene and Spiroisatin Hybrids as Promising Cytotoxic, Antifungal and Antiviral Compounds

Yaneth M. Brand ; Vladimir V. Kouznetsov ; Carlos E. Puerto ; Vicky C. R. Linares ; Verónica T. Castaño; Liliana Betancur-Galvis

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A series of combretastatin A-4 hybrids were designed, synthesized and evaluated in order to explore new cytotoxic, antifungal and antiviral agents.

https://dx.doi.org/10.21577/0103-5053.20190265

Published online: November 26, 2019

 

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J. Braz. Chem. Soc. 2020, 31(5), 1011-1020

Regenerated Cellulose Membrane from Peanut Shell for Biodiesel Purification

Ana Maria S. Reis; Andressa T. Vieira; Allyson L. R. Santos; Marcos V. Ferreira; Antônio C. F. Batista; Rosana M. N. Assunção; Guimes Rodrigues Filho; Elaine A. M. Ribeiro; Anizio M. Faria

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Preparation of regenerated cellulose membrane from peanut shell for purification of biodiesel.

https://dx.doi.org/10.21577/0103-5053.20190267

Published online: December 2, 2019

 

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Total access: 1104


J. Braz. Chem. Soc. 2020, 31(5), 1021-1029

Variability of the Volatile Organic Compounds of Achillea millefolium L. According to the Collection Time, Type of Polyethylene Packaging and Storage Period

Aurilene A. Vasconcelos; Elenilson G. Alves Filho; Tigressa H. S. Rodrigues; Adriely F. Vieira; Renato Innecco; Gisele S. Silva; Guilherme J. Zocolo

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The metabolic profile of Achillea millefolium essential oil by chemometric analysis on gas chromatography-mass spectrometry (GC-MS) data in six different collection times and five storage periods, employing three different polyethylene packages, viz. white, silver and black.

https://dx.doi.org/10.21577/0103-5053.20190268

Published online: December 3, 2019

 

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Total access: 998


J. Braz. Chem. Soc. 2020, 31(5), 1030-1042

3-Aminofurostane Alkaloids from Solanum paniculatum ("Jurubeba Verdadeira") Roots

Tania M. S. Silva; Telma M. G. Silva; Maria F. Agra; Celso A. Camara

How to cite this article

 

Novel aminofurostane alkaloids were identified from Solanum paniculatum roots.

https://dx.doi.org/10.21577/0103-5053.20190269

Published online: December 10, 2019

 

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Total access: 1763


J. Braz. Chem. Soc. 2020, 31(5), 1043-1054

Assessment of Atmospheric PM10 Pollution Levels and Chemical Composition in Urban Areas near the 2016 Olympic Game Arenas

Elizanne P. S. Justo; Maria Fernanda C. Quijano; Karmel Beringui; Tatiana D. Saint'Pierre; Adriana Gioda

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This work describes the sampling and chemical analysis scheme of collected particulate matter (PM) and the study site picture.

https://dx.doi.org/10.21577/0103-5053.20190270

Published online: December 6, 2019

 

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Total access: 1940


J. Braz. Chem. Soc. 2020, 31(5), 1055-1063

Determination of Methanol in Gasoline and Ethanol Fuels by High-Performance Liquid Chromatography

Gabriella P. Dias; Rafael C. dos Santos; Renato C. Carvalho; Cristiane G. de Souza; Amanda P. F. dos Santos; Débora F. de Andrade; Luiz A. d'Avila

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Simple and fast methodology for detection and quantification of adulterant methanol in gasoline and ethanol fuel.

https://dx.doi.org/10.21577/0103-5053.20190272

Published online: December 12, 2019

 

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J. Braz. Chem. Soc. 2020, 31(5), 1064-1077

Theoretical and Experimental Investigations on Inclusion Complex β-Cyclodextrin and Sulcatone: A Cardiovascular Activity Evaluation

Ivan S. Silva; Eduardo L. Feitosa; Márcio E. P. Santos; Raiane M. Silva; Márcio S. Rocha; Francisco I. da Silva; Francisco C. A. Lima; Ana Maria S. Costa; Péricles B. Alves; Samuel A. A. de Sousa; Aldeídia P. Oliveira; Sidney G. de Lima

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Sulcatone inclusion complex/β-cyclodextrin (β-CD): physicochemical characterization, theoretical study and evaluation of vasorelaxant activity.

https://dx.doi.org/10.21577/0103-5053.20190273

Published online: December 12, 2019

 

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Short Report J. Braz. Chem. Soc. 2020, 31(5), 1078-1085

Influence of the Capping Agent PVP of the Outer Layer of Pd Nanocubes Surface on the Catalytic Hydrogenation of Unsaturated C−C Bonds

Suelen C. Buratto; Eloah Latocheski; Daniela C. de Oliveira; Josiel B. Domingos

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The number of washing cycles in the removal of capping agent polyvinylpyrrolidone (PVP) excess present in the outer layers of palladium nanocubes, in the post-synthesis purification step, is shown to strongly affect the catalytic activity on the hydrogenation reaction of unsaturated C−C bonds.

https://dx.doi.org/10.21577/0103-5053.20190250

Published online: October 29, 2019

 

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J. Braz. Chem. Soc. 2020, 31(5), 1086-1092

Easy Epoxidation of Monoterpenes from Common Starting Materials

John H. Bermudez; Giovanni Rojas ; Ricardo B. Benitez; Jaime M. Franco

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Epoxidation of monoterpenes by the in situ production of a peroxyacid without the use of catalyst at room temperature produced up to 75% pure epoxide.

https://dx.doi.org/10.21577/0103-5053.20190253

Published online: October 30, 2019

 

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Online version ISSN 1678-4790 Printed version ISSN 0103-5053
Journal of the Brazilian Chemical Society
JBCS Editorial and Publishing Office
University of Campinas - UNICAMP
13083-970 Campinas-SP, Brazil

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