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vol. 31, No. 9, 2020, p. 1759-1963

 

The 2-amino-1,4-naphthoquinone derivatives are interesting and versatile compounds with relevant biological activity, including antibacterial activity. The most significant effect was observed against Klebsiella pneumoniae positive β-lactamase. In addition, the experimental and theoretical affinity of the three most potential bactericidal compounds with human serum albumin indicated spontaneous and moderate interaction, which makes it possible to transport them in the human bloodstream. Details are presented in the Article Antibacterial Activity of 2-Amino-1,4-naphthoquinone Derivatives against Gram-Positive and Gram-Negative Bacterial Strains and Their Interaction with Human Serum Albumin by Carla C. da Silva, Otávio A. Chaves, Rojane O. Paiva, Gisela L. da Costa, José Carlos Netto-Ferreira and Aurea Echevarria on page 1838.


Cover Article
J. Braz. Chem. Soc. 2020, 31(9), 1838-1851

Antibacterial Activity of 2-Amino-1,4-naphthoquinone Derivatives against Gram‑Positive and Gram-Negative Bacterial Strains and Their Interaction with Human Serum Albumin

Carla C. da Silva; Otávio A. Chaves ; Rojane O. Paiva; Gisela L. da Costa; José Carlos Netto-Ferreira; Aurea Echevarria

How to cite this article

The 2-amino-1,4-naphthoquinone derivatives are interesting and versatile compounds with relevant biological activity, including antibacterial activity. The most significant effect was observed against Klebsiella pneumoniae positive β-lactamase. In addition, the experimental and theoretical affinity of the three most potential bactericidal compounds with human serum albumin indicated spontaneous and moderate interaction, which makes it possible to transport them in the human bloodstream. Details are presented in the Article Antibacterial Activity of 2-Amino-1,4-naphthoquinone Derivatives against Gram-Positive and Gram-Negative Bacterial Strains and Their Interaction with Human Serum Albumin by Carla C. da Silva, Otávio A. Chaves, Rojane O. Paiva, Gisela L. da Costa, José Carlos Netto-Ferreira and Aurea Echevarria on page 1838.

https://dx.doi.org/10.21577/0103-5053.20200070

Published online: April 16, 2020
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Communication J. Braz. Chem. Soc. 2020, 31(9), 1759-1763

Determination of Ethanol in Gel Hand Sanitizers Using Mid and Near Infrared Spectroscopy

Fernando S. Fonseca Jr.; Lívia R. e Brito ; Maria Fernanda Pimentel; Leila B. Leal

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Two methods based on mid and near infrared spectroscopy associated with chemometrics were developed to determine ethanol content in alcohol-based gel hand-sanitizers.

https://dx.doi.org/10.21577/0103-5053.20200115

Published online: June 16, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1764-1770

Drawing Electrochemical Sensors Using a 3D Printing Pen

Rafael M. Cardoso; Sílvia V. F. Castro ; Jéssica S. Stefano ; Rodrigo A. A. Muñoz

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We demonstrate that a 3D printing pen (commonly used as a toy for kids) can be used to the fast drawing of low-cost electrochemical thermoplastic sensors in any desirable design using conductive filaments.

https://dx.doi.org/10.21577/0103-5053.20200129

Published online: June 26, 2020

 

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Articles J. Braz. Chem. Soc. 2020, 31(9), 1771-1777

New Strategy for Streptavidin Detection Using AuNRs/PAAm Hydrogel Composites

Jean H. de Oliveira; Johny P. Monteiro; Paulo H. M. Buzzetti ; Bento P. Cabral Jr.; Eduardo Radovanovic ;
Emerson M. Girotto

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The figure presents a new hydrogel/gold nanorods system for the detection of streptavidin by specific interaction using the localized surface plasmon resonance (LSPR) phenomenon.

https://dx.doi.org/10.21577/0103-5053.20200032

Published online: March 3, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1778-1786

A Highly Selective Fluorescent Chemosensor for Al3+ Based on 2,2':6',2"-Terpyridine with a Salicylal Schiff Base

Jiacheng Xu; Hui Li ; Liangwei Li; Jianzhi Wang; Feng Wang; Luying He

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New 2,2':6',2"-terpyridines-derived Schiff base chemosensors (TPySSB) for the highly selective determination of Al3+ in ethanol.

https://dx.doi.org/10.21577/0103-5053.20200063

Published online: April 7, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1787-1795

Zinc Hexacyanoferrate/Multi-Walled Carbon Nanotubes Films for Rechargeable Aqueous Batteries

Murillo N. T. Silva ; José D. Ardisson; José D. Fabris; Edson Nossol

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Multi-walled carbon nanotube/zinc hexacyanoferrate (MWCNT/ZnHCF) battery electrode based on interfacial synthesis promotes intimate contact between the components with good electrical conductivity, and an increasing of eight-fold in the electrode capacity compared with ZnHCF electrode.

https://dx.doi.org/10.21577/0103-5053.20200064

Published online: April 7, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1796-1804

Mechanistic Investigation of DBU-Based Ionic Liquids for Aza-Michael Reaction: Mass Spectrometry and DFT Studies of Catalyst Role

Augusto A. Cândido; Thiago C. Rozada; Andrew M. F. Rozada; João R. B. Souza; Eduardo J. Pilau ; Fernanda A. Rosa; Ernani A. Basso ; Gisele F. Gauze

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Acid hydrogen in the ionic liquid (IL) and the ability of the anion to carry out a hydrogen bond with arylamine are fundamental for the catalysis.

https://dx.doi.org/10.21577/0103-5053.20200066

Published online: April 9, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1805-1814

Synthesis and Evaluation of Nematicidal Activity of Compounds Derived from Norbornadiene

Anni C. S. Gomes; Antonio J. Demuner ; Elson S. Alvarenga ; João P. E. Gondim; Andressa R. Fonseca; Dalila S. Buonicontro; Eduardo J. Pilau ; Evandro Silva

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Norbornadiene derivatives, infested roots, nematode live and nematode dead.

https://dx.doi.org/10.21577/0103-5053.20200067

Published online: April 9, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1815-1824

Synthesis, Characterization, Absorption and Fastness Properties of Novel Monoazo Dyes Derived from 1-Phenyl-3-amino-4-(2-thiazolilazo)pyrazol-5-one

Fatma Erol

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The absorption values (λmax) of synthesised dyes were not related to the polarity of solvents but instead to the proton-donor and acceptor properties of solvents, which reinforced the ionisation rather than tautomerism and they were more sensitive towards acids. The dyes may be in cationic and anionic form totally or partially in acidic and basic medium. The image shows the tautomeric structures and ionic forms of 1-phenyl-3-amino-4-(2-thiazolilazo)pyrazol-5-one.

https://dx.doi.org/10.21577/0103-5053.20200068

Published online: April 14, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1825-1837

Phytochemical Analysis, Multi-Element Composition and Biological Activities of Extracts and Lupenone from Albizia inundata (Mart.) Barneby & J.W.Grimes

Eberson M. J. Andrade; Jéssica S. Teixeira; Dahara K. C. Silva; Tatiana B. dos Santos; Maria G. A. Korn; Hugo N. Brandão; Caline G. Ferraz; Cássio S. Meira; Milena B. P. Soares; Elisava T. Guimarães; Lourdes C. S. Neta; Aníbal F. S. Júnior

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Lupenone was isolated, for the first time, from Albizia inundata (Mart.) Barneby & J.W.Grimes by one-dimensional nuclear magnetic resonance. Extracts and lupenone from A. inundata showed antimicrobial (antibacterial, antifungal and antiparasitic) activities and, multi-element composition was evaluated using inductively coupled plasma optical emission spectrometry (ICP OES).

https://dx.doi.org/10.21577/0103-5053.20200069

Published online: April 14, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1838-1851

Antibacterial Activity of 2-Amino-1,4-naphthoquinone Derivatives against Gram‑Positive and Gram-Negative Bacterial Strains and Their Interaction with Human Serum Albumin

Carla C. da Silva; Otávio A. Chaves ; Rojane O. Paiva; Gisela L. da Costa; José Carlos Netto-Ferreira; Aurea Echevarria

How to cite this article

 

A series of 2-amino-1,4-naphthoquinone derivatives (NQA-NQF) was evaluated as potential antibacterial. NQF was identified as the most active compound against K. pneumoniae positive β-lactamase (minimum inhibitory concentration (MIC) = 31.2 µg mL-1) and presented good parameters of interaction with human serum albumin (HSA).

https://dx.doi.org/10.21577/0103-5053.20200070

Published online: April 16, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1852-1858

Crystallographic Changes Accompanying the Verwey Transition in a Magnetite from Steatite

Fernando D. da Silva ; Sandra L. Nogueira ; José D. Fabris; Antônio T. Goulart; Paulo R. C. Couceiro

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The scanning electron microscopy image shows a magnetite crystal of natural origin. In the X-ray diffraction it is possible to visualize the crystalline transition of this magnetite at low temperature (15 K). Highlighted the evolution of the Verwey transition as a function of temperature and its change from cubic to monoclinic structure.

https://dx.doi.org/10.21577/0103-5053.20200073

Published online: April 23, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1859-1872

Accessing Basic Sites on Modified CoFe2O4 Nanoparticles: Addressing the Selective Oxidation of Benzyl Alcohol and Unraveling the Au:Pd Ratio Effects by XPS

Laíse N. S. Pereira; Marco A. S. Garcia ; Jennifer Rozendo; Pedro Vidinha; Alfredo Duarte ; Carla V. R. de Moura ; Edmilson M. de Moura

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AuPd nanoparticles were immobilized onto a basic CoFe2O4-modified magnetic support and presented remarkable activity/selectivity on oxidation reactions.

https://dx.doi.org/10.21577/0103-5053.20200075

Published online: April 23, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1873-1882

Electroanalytical Method for Determination of Trace Metals in Struvite Using Electrochemically Treated Screen-Printed Gold Electrodes

Maria L. S. Vasconcellos; Diego P. Rocha; Sílvia V. F. Castro; Luiz R. G. Silva; Rodrigo A. A. Muñoz ; Marcos B. J. G. Freitas; Rafael Q. Ferreira

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This study presents a new electrochemical method for determination of trace metals (PbII, CuII and HgII) in struvite samples (natural fertilizer produced from urine). For this, we propose the use of square-wave anodic stripping voltammetry (SWASV) technique associated with electrochemically treated screen-printed gold electrodes.

https://dx.doi.org/10.21577/0103-5053.20200081

Published online: May 5, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1883-1890

Omega-3 and Omega-6 Determination in Nile Tilapia's Fillet Based on MicroNIR Spectroscopy and Multivariate Calibration

Dayane A. dos Santos; Aline Coqueiro ; Thays R. Gonçalves; Jonathan C. Carvalho; Jailton S. Bezerra Jr.; Makoto Matsushita; Carlos A. L. de Oliveira; Paulo H. Março; Patrícia Valderrama ; Ricardo P. Ribeiro

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Near-infrared/partial least squares (NIR/PLS) calibration developed to predict omega-3 and omega-6 in fillets of Nile tilapias packed under vacuum.

https://dx.doi.org/10.21577/0103-5053.20200082

Published online: May 5, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1891-1897

Effects of Temperature and Concentration on the Determination of PET Viscosity

Felipe Z. da Silva ; Izabella C. Bastos; Daniela B. Hirata

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The work consisted of an analytical investigation, based on statistical concepts, to validate a model that described the viscosity of a polymeric polyethylene terephthalate (PET) solution.

https://dx.doi.org/10.21577/0103-5053.20200084

Published online: May 7, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1898-1907

Optimization and Validation of LLE-LTP and QuEChERS Methodologies for Determining 2,4-D in Water Samples

Lucas V. P. Freitas ; Lázaro C. Sicupira; Gevany P. Pinho; Flaviano O. Silvério

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Graphical abstract represents liquid-liquid extraction with low-temperature partition (LLE-LTP) and quick, easy, cheap, effective, rugged, and safe (QuEChERS) methodologies combined with high-performance liquid chromatography with diode array detector (HPLC-DAD) used in the present study for determining 2,4-dichlorophenoxyacetic acid (2,4-D) in water samples.

https://dx.doi.org/10.21577/0103-5053.20200086

Published online: May 12, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1908-1916

Dereplication of Aporphine Alkaloids by UHPLC-HR-ESI-MS/MS and NMR from Duguetia lanceolata St.-Hil (Annonaceae) and Antiparasitic Activity Evaluation

Erick P. Dantas; Jackson Monteiro; Lívia S. de Medeiros; Maiara M. Romanelli; Maiara Amaral; Andre G. Tempone; João Henrique G. Lago ; Marisi G. Soares; Patricia Sartorelli

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The dereplication of alkaloidic phase from Duguetia lanceolata performed by ultra-high performance liquid chromatography high resolution electrospray ionization tandem mass spectrometry (UHPLC-HR-ESI-MS/MS) and 1H nuclear magnetic resonance (NMR) allowed the identification of eight aporphine alkaloids. Some fraction composed by alkaloids show antiparasitic activity.

https://dx.doi.org/10.21577/0103-5053.20200089

Published online: May 15, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1917-1925

Synthesis and Evaluation of the Fungal Activity of New Pyrazole-Carboxamides against Colletotrichum gloeosporioides

Edwin González-López; Jhair León-Jaramillo; Jorge Trilleras ; Carlos D. Grande-Tovar; Yeimmy Peralta-Ruiz; Jairo Quiroga

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Influence of four pyrazole-carboxamide derivatives in parameters growth of C. gloeosporioides BA3 in potato dextrose agar (PDA).

https://dx.doi.org/10.21577/0103-5053.20200092

Published online: May 19, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1926-1938

Profiling the Cymbopogon nardus Ethanol Extract and Its Antifungal Potential against Candida Species with Different Patterns of Resistance

Luciani G. de Toledo ; Matheus A. S. Ramos ; Larissa Spósito ; Elza M. Castilho ; Fernando R. Pavan ; Érica O. Lopes ; Isabel C. da Silva ; Guilherme J. Zocolo ; Paulo R. V. Ribeiro ; Fernando B. Oda ; Juhan A. S. Pereira; André G. dos Santos ; Taís M. Bauab ; Margarete T. G. de Almeida

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Ethanol extract from leaves of Cymbopogon nardus (citronella) contains phenolic compounds that exerted significant antifungal activity.

https://dx.doi.org/10.21577/0103-5053.20200093

Published online: May 20, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1939-1948

Lignocellulosic Residues from the Brazilian Juice Processing Industry as Novel Sustainable Sources for Bioenergy Production: Preliminary Assessment Using Physicochemical Characteristics

José L. F. Alves ; Emmely O. da Trindade; Jean C. G. da Silva ; Guilherme D. Mumbach ; Ricardo F. Alves ; José M. Barbosa Filho ; Petrônio F. de Athayde-Filho; Rennio F. de Sena

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Underutilized lignocellulosic residues from the Brazilian juice processing industry as promising feedstocks in thermochemical processes.

https://dx.doi.org/10.21577/0103-5053.20200094

Published online: May 20, 2020

 

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J. Braz. Chem. Soc. 2020, 31(9), 1949-1954

Polyurethanes Obtained by Reacting 1,6-HDI with Monoglycerides from Babassu Oil: A DFT Study

Francisco I. da Silva; Égil Sá ; José M. E. de Matos

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Polyurethane by reacting 1,6-hexamethylenediisocyanate (1,6-HDI) with 2-monolaurin, which is the most abundant monoacylglycerol in the babassu oil, occurs by a concerted mechanism. The polymerization occurs by adding urethane monomer, instead of each of the co-monomer.

https://dx.doi.org/10.21577/0103-5053.20200096

Published online: May 22, 2020

 

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Short Report J. Braz. Chem. Soc. 2020, 31(9), 1955-1963

Evaluation of Brazilian Monovarietal Extra Virgin Olive Oils Using Digital Images and Independent Component Analysis

Thays R. Gonçalves; Larissa N. Rosa; Paulo H. Março; Luiz F. O. da Silva; Sandra T. M. Gomes; Makoto Matsushita; Patrícia Valderrama

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Brazilian monovarietal extra virgin olive oil: an unsupervised pattern recognition approach based on red, green and blue (RGB) channels and independent component analysis.

https://dx.doi.org/10.21577/0103-5053.20200083

Published online: May 7, 2020

 

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Online version ISSN 1678-4790 Printed version ISSN 0103-5053
Journal of the Brazilian Chemical Society
JBCS Editorial and Publishing Office
University of Campinas - UNICAMP
13083-970 Campinas-SP, Brazil

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