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vol. 32, No. 2, 2021, p. 237-453

 

A molecularly imprinted electrochemical sensor for determination of isoamyl alcohol was developed by modifying the glassy carbon electrode (GCE) with gold nanoparticles (AuNPs) and reduced graphene oxide (RGO). The modification of the GCE increased the electron transfer rate and the electrode surface area, which improves the performance of the sensor. The MIP-AuNPs-RGO/GCE showed low limit of detection and good amperometric sensitivity. Details are presented in the Article Molecularly Imprinted Polypyrrole on Glassy Carbon Electrode Modified with Reduced Graphene Oxide and Gold Nanoparticles for Isoamyl Alcohol Analysis in Fusel Oil by Thiago M. Mariano, Maísa A. Beluomini and Nelson R. Stradiotto on page 249.


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J. Braz. Chem. Soc. 2021, 32(2), 249-259

Molecularly Imprinted Polypyrrole on Glassy Carbon Electrode Modified with Reduced Graphene Oxide and Gold Nanoparticles for Isoamyl Alcohol Analysis in Fusel Oil

Thiago M. Mariano ; Maísa A. Beluomini ; Nelson R. Stradiotto

How to cite this article

A molecularly imprinted electrochemical sensor for determination of isoamyl alcohol was developed by modifying the glassy carbon electrode (GCE) with gold nanoparticles (AuNPs) and reduced graphene oxide (RGO). The modification of the GCE increased the electron transfer rate and the electrode surface area, which improves the performance of the sensor. The MIP-AuNPs-RGO/GCE showed low limit of detection and good amperometric sensitivity. Details are presented in the Article Molecularly Imprinted Polypyrrole on Glassy Carbon Electrode Modified with Reduced Graphene Oxide and Gold Nanoparticles for Isoamyl Alcohol Analysis in Fusel Oil by Thiago M. Mariano, Maísa A. Beluomini and Nelson R. Stradiotto on page 249.

https://dx.doi.org/10.21577/0103-5053.20200174

Published online: August 26, 2020
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Articles J. Braz. Chem. Soc. 2021, 32(2), 237-248

Mapping Biochemical Pathways in Maytenus ilicifolia (Celastraceae) through Integrated Proteomics and Histochemistry

Vânia A. F. F. M. Santos ; Nathalia B. Dias; Simone P. Teixeira; Mario S. Palma; Maysa Furlan

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Proteomic and histochemical approaches aimed to identify the main biosynthetic pathways active in M. ilicifolia and provide evidences of differential compartmentalization of quinonemethide triterpenes and sesquiterpene pyridine alkaloids.

https://dx.doi.org/10.21577/0103-5053.20200173

Published online: August 25, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 249-259

Molecularly Imprinted Polypyrrole on Glassy Carbon Electrode Modified with Reduced Graphene Oxide and Gold Nanoparticles for Isoamyl Alcohol Analysis in Fusel Oil

Thiago M. Mariano ; Maísa A. Beluomini ; Nelson R. Stradiotto

How to cite this article

 

Molecular imprinting of polypyrrole on glassy carbon electrode modified with reduced graphene oxide and gold nanoparticles for the selective and sensitive determination of isoamyl alcohol.

https://dx.doi.org/10.21577/0103-5053.20200174

Published online: August 26, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 260-268

Interaction of Pb, Ni and Cd with Aquatic Humic Substances of Amazonian Blackwater Rivers

Isabela C. Constantino; Juliana G. Viana; Priscila A. Teixeira; Altair B. Moreira; Giovanna P. Gama; Fabiana M. M. Paschoal; Ézio Sargentini Jr.; Márcia C. Bisinoti

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Aquatic humic substances (AHSs) were extracted from two blackwater rivers (Negro and Carú) of the Amazon region and their complexation capacities (CC) with NiII, CdII and PbII were determined using ultrafiltration system with tangential flow. The seasonal influence was observed in AHS from Carú River, which during dry season showed low humification degree. AHS from Negro River had the highest CC for all metal ions tested. Transport, bioavailability and toxicity of the metal ions tested can be different in these blackwater rivers.

https://dx.doi.org/10.21577/0103-5053.20200176

Published online: August 31, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 269-276

Determining Methamphetamine in Urine by Molecularly Imprinted Polymer Assisted Paper Spray Ionization Mass Spectrometry

Talita P. de Brito; Deborah V. A. de Aguiar; Igor Pereira ; Boniek G. Vaz

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Molecularly imprinted polymer was synthesized on the surface of a triangular paper to provide enhanced analysis of methamphetamine in urine by paper spray ionization mass spectrometry.

https://dx.doi.org/10.21577/0103-5053.20200177

Published online: September 2, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 277-286

A Green Procedure Using Disposable Pipette Extraction to Determine Polycyclic Aromatic Sulfur Heterocycles in Water Samples and Solid Petrochemical Residues

Karine O. Garcia; Morgana Frena; Otávio R. Bittencourt; Hérica A. Magosso; Eduardo Carasek; Luiz A. S. Madureira

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A new approach using disposable pipette extraction technique to determine polycyclic aromatic sulfur heterocycles in lagoon water samples and leachate of solid petrochemical residues.

https://dx.doi.org/10.21577/0103-5053.20200178

Published online: September 3, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 287-298

Properties of Cu-Co Composite Catalysts for Synthesis of Aliphatic Alcohols

Mayya V. Kulikova ; Mariya V. Chudakova; Mikhail I. Ivantsov; Alexei E. Kuz'min; Alla Yu. Krylova; Anton L. Maksimov

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Cu-Co-containing cellulose-based carbon composite materials were formed by the matrix isolation method. Composites are highly active in the synthesis of alcohols from CO and H2.

https://dx.doi.org/10.21577/0103-5053.20200179

Published online: September 4, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 299-310

Spatial Distribution and Pollution Assessment of Trace Elements Pb, Cu, Ni, Fe and As in the Surficial Water of Staring Bay, Indonesia

Alrum Armid ; Ryuichi Shinjo; Amadhan Takwir; Ruslan Ruslan; Anugrah R. Wijaya

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Staring Bay has been contaminated by Pb and Fe due to anthropogenic activities (industries and brackish ponds) around the bay.

https://dx.doi.org/10.21577/0103-5053.20200180

Published online: September 4, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 311-319

Rapid and Inexpensive Colorimetric Detection of Total Serum Protein Using Microzone Plates Wax-Printed on Polyester Films

Karoliny A. Oliveira; Thiago M. G. Cardoso; Helton F. Oliveira; Maria C. S. Fioravanti ; Wendell K. T. Coltro

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A colorimetric method based on biuret assay was performed on wax printed polyester microzone plates for total serum protein analysis.

https://dx.doi.org/10.21577/0103-5053.20200181

Published online: September 8, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 320-328

Protein Removal from Natural Rubber Latex with Fe3O4@Al2O3 Nanoparticle

I P. Mahendra ; Mai K. Linh; Nguyen N. Thang; Vu T. Thuy; Le T. Trang; Le X. Thinh; Nguyen T. H. Phuong; Nguyen T. Ha ; Nghiem T. Thuong ; Seiichi Kawahara ; Yoshimasa Yamamoto ; Phan T. Nghia

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Nanoparticle of Fe3O4@Al2O3 was prepared through co-precipitation of magnetic iron oxide nanoparticle and followed by coating process of alumina on the surface of magnetic iron oxide nanoparticle.

https://dx.doi.org/10.21577/0103-5053.20200182

Published online: September 9, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 329-336

Development of a Methodology Based on Extraction Induced by Emulsion Breaking for Copper Determination in Gasohol by Graphite Furnace Atomic Absorption Spectrometry

Valdinei S. de Souza ; Leonardo S. G. Teixeira; Maria G. A. Korn ; Uillian M. F. M. Cerqueira; Marcos A. Bezerra

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Copper determination by graphite furnace atomic absorption spectrometry (GF AAS) in gasohol samples after extraction induced by emulsion breaking to separate the analyte from the organic phase.

https://dx.doi.org/10.21577/0103-5053.20200183

Published online: September 9, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 337-346

Mineral Nutrients and Plant-Fungal Interaction in Cocoa Trees (Theobroma cacao L.)

Hélio R. Sousa Filho; Raildo M. de Jesus; Marcos A. Bezerra ; Vinnícius H. C. da Silva; André L. S. da Silva Jr.; Juscelia P. S. Alves; Gregório M. Santana; José O. de Souza Jr.

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Determination of mineral nutrient concentrations in healthy leaves and vegetative broom leaves in cocoa, relationship between disease and nutritional composition.

https://dx.doi.org/10.21577/0103-5053.20200184

Published online: September 9, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 347-354

Morita-Baylis-Hillman Reaction with 7-Chloroquinoline Derivatives‑New Compounds with Potential Anticancer Activity

João Paulo G. Oliveira; Guilherme S. Caleffi ; Everton P. Silva; Maísa C. Coelho; Aleff C. Castro ; Rhuan K. S. Mendes; Tayná R. Olegário; Claudio G. Lima-Junior ; Mario L. A. A. Vasconcellos; Júlia L. C. Souza; Sílvia M. Souza; Gardênia C. G. Militão; Boniek G. Vaz ; Ruver R. F. Ramalho

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Modification of Morita-Baylis-Hillman adducts (MBHA) with 7-chloroquinoline giving derivatives with improved anticancer activity in relation to the MBHA previously reported and used.

https://dx.doi.org/10.21577/0103-5053.20200185

Published online: September 15, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 355-362

Preparation of Poly(3-hydroxybutyrate-b-ε-caprolactone) by Reactive Extrusion and Production of Electrospun Fibrous Mats

Katia Y. Sakaguti ; Shu H. Wang

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Poly(3-hydroxybutyrate) (PHB) obtained from sugarcane was modified by reactive extrusion with poly(ε-caprolactone) (PCL), producing copolymer that can be electrospun, resulting in ultrafine fibrous mats.

https://dx.doi.org/10.21577/0103-5053.20200186

Published online: September 11, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 363-375

Characterization, Source Apportionment and Health Risk Assessment of PM2.5 for a Rural Classroom in the Amazon: A Case Study

Karenn S. Fernandes ; Erickson O. dos Santos; Ricardo H. M. Godoi; Carlos I. Yamamoto; Cybelli G. G. Barbosa; Rodrigo A. F. Souza; Cristine M. D. Machado

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Indoor and outdoor fine particulate matter (PM2.5) concentration and chemical composition were investigated in a classroom of a rural city in the Amazon region. The picture represents the main sources of PM2.5, the infiltration of particles through the windows and their accumulation inside the classroom.

https://dx.doi.org/10.21577/0103-5053.20200188

Published online: September 16, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 376-384

Er3+/Yb3+-Doped GdVO4 Obtained by the Non-Hydrolytic Sol-Gel Route and Potential Application as Up-Conversion Thermometer

Maria F. Ferreira; Kalil Z. R. de Sousa; Wagner L. Massarotto; Emiliane G. Ricci; Emerson H. de Faria; Katia J. Ciuffi ; Dragutin Sevic; Lucas A. Rocha; Eduardo J. Nassar

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Energy level diagrams for Er3+ and Yb3+, detail of the thermally coupled level. The figure shows the up-conversion mechanism between Er3+ and Yb3+ lanthanides and the thermally coupled level that enables the application of the system as thermometer.

https://dx.doi.org/10.21577/0103-5053.20200189

Published online: September 17, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 385-394

Evaluation of the Seasonality and Extraction Method on the Polar Extracts of Croton grewioides Baill. by Chromatogram Fingerprinting and Isolation of a New Triglycosylated Flavonoid

Vilma M. J. Prado; Raphael A. de Jesus; Julio M. A. Oliveira; Camila S. A. Pereira; Arie F. Blank; Edenir R. Pereira-Filho ; Quezia B. Cass ; Juliana M. de Lima; Antonio G. Ferreira; Paulo C. L. Nogueira; Valéria R. S. Moraes

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Seasonality and extraction method effects on chemical profile of Croton grewioides Baill. and isolation of a new triglycosylated flavonoid derivative.

https://dx.doi.org/10.21577/0103-5053.20200190

Published online: September 18, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 395-404

Theoretical Study of the Reactivity of Phenyl Radicals Toward Enol Acetates

Leonardo S. A. Carneiro ; Leticia H. S. P. C. Real ; Camilla D. Buarque ; Pierre M. Esteves

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The reactivity of phenyl radicals toward enol acetates could be explained by the influence of polar and steric effects in the early transition state.

https://dx.doi.org/10.21577/0103-5053.20200192

Published online: September 21, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 405-412

An Alternative Description for the Electronegativity Difference in Binary Ionic Solids

Heveson Lima ; Douglas Ferreira; Adelmo S. Souza; Marcos A. C. dos Santos

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This model presents an alternative way of discussing electronegativity based on how ions organize themselves, through the packing factor, and how electrons are transferred in the process of chemical bonding, through the charge factor.

https://dx.doi.org/10.21577/0103-5053.20200193

Published online: September 23, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 413-428

Aqueous Extract of Cumaru (Dipteryx odorata) Seeds as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Solution

Viviane M. Teixeira ; Gustavo A. de Oliveira; Michelle J. C. Rezende ; Eliane D'Elia

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The cumaru extract proved to be an excellent corrosion inhibitor. The high molecular weight fraction (HMWF) showed an inhibition efficiency better than the aqueous extract, which suggests that the macromolecules are responsible for inhibiting corrosion.

https://dx.doi.org/10.21577/0103-5053.20200194

Published online: September 28, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 429-436

Crystal Structure and Hirshfeld Surface Analysis of 1,4-Pentadien-3-one, (1E,4E)-1,5-diphenyl-2-(2,4-dinitrophenyl)hydrazone

Carolina B. P. Ligiéro; Pamella M. Monte; Tiago L. da Silva; José C. Barros

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Molecular structure of 1,4-pentadien-3-one, (1E,4E)-1,5-diphenyl-2-(2,4-dinitrophenyl)hydrazone, analyzed by X-ray crystallography.

https://dx.doi.org/10.21577/0103-5053.20200195

Published online: September 30, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 437-446

Yellow Mombin (Spondias mombin L.) Seeds from Agro-Industrial Waste as a Novel Adsorbent for Removal of Hexavalent Chromium from Aqueous Solutions

Adilson S. Santos ; Tereza S. M. Santos ; Valfredo A. Lemos ; Alexilda O. de Souza

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The biosorbent (BMC) produced from yellow mombin (Spondias mombin L.) was characterized and then used for removing chromium(VI) in an aqueous solution. The kinetic data were better suited to the Elovich model.

https://dx.doi.org/10.21577/0103-5053.20200196

Published online: September 30, 2020

 

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J. Braz. Chem. Soc. 2021, 32(2), 447-453

Antileishmanial Acetylene Fatty Acid and Acetogenins from Seeds of Porcelia macrocarpa

Ivanildo A. Brito; Emerson A. Oliveira; Mariana H. Chaves; Fernanda Thevenard; André F. Rodrigues-Oliveira ; Gustavo Barbosa-Reis; Patricia Sartorelli; Diogo Oliveira-Silva ; Andre G. Tempone; Thais A. Costa-Silva; João Henrique G. Lago

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Five acetylene derivatives (1-5), including three unknowns (1, 3 and 4), were isolated from seeds of Porcelia macrocarpa (Annonaceae). All isolated compounds demonstrated selectivity towards intracellular amastigotes of Leishmania (L.) infantum, especially compounds 2-4 with superior activity of that determined to positive control miltefosine. These compounds could be considered as candidates in the development of new drugs for treatment of neglected diseases.

https://dx.doi.org/10.21577/0103-5053.20200197

Published online: October 2, 2020

 

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Online version ISSN 1678-4790 Printed version ISSN 0103-5053
Journal of the Brazilian Chemical Society
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University of Campinas - UNICAMP
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