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vol. 32, No. 5, 2021, p. 917-1136

 

The perspective of the review is to contribute to the scientific community with examples, tips, and details of modern development in the field of catalysis and with a complete illustration of the routes which may be effective for the planning of the ubiquitous C-H bond activation and its use for the synthesis of relevant organic molecules. Details are presented in the Review A Catalysis Guide Focusing on C-H Activation Processes by Renato L. Carvalho, Gleiston G. Dias, Cynthia L. M. Pereira, Pintu Ghosh, Debabrata Maiti and Eufrânio N. da Silva Júnior on page 917.


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J. Braz. Chem. Soc. 2021, 32(5), 917-952

A Catalysis Guide Focusing on C-H Activation Processes

Renato L. Carvalho; Gleiston G. Dias; Cynthia L. M. Pereira; Pintu Ghosh; Debabrata Maiti ; Eufrânio N. da Silva Júnior

How to cite this article

The perspective of the review is to contribute to the scientific community with examples, tips, and details of modern development in the field of catalysis and with a complete illustration of the routes which may be effective for the planning of the ubiquitous C-H bond activation and its use for the synthesis of relevant organic molecules. Details are presented in the Review A Catalysis Guide Focusing on C-H Activation Processes by Renato L. Carvalho, Gleiston G. Dias, Cynthia L. M. Pereira, Pintu Ghosh, Debabrata Maiti and Eufrânio N. da Silva Júnior on page 917.

https://dx.doi.org/10.21577/0103-5053.20210025

Published online: February 19, 2021
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Review J. Braz. Chem. Soc. 2021, 32(5), 917-952

A Catalysis Guide Focusing on C-H Activation Processes

Renato L. Carvalho; Gleiston G. Dias; Cynthia L. M. Pereira; Pintu Ghosh; Debabrata Maiti ; Eufrânio N. da Silva Júnior

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A C-H activation process represents one of the most advanced tool in the field of organic synthesis nowadays, and it requires knowledge that should be studied and learned. Therefore, carrying out a C-H activation reaction in the right direction, following the right steps, can improve its performance and guarantee plausible results.

https://dx.doi.org/10.21577/0103-5053.20210025

Published online: February 19, 2021

 

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Articles J. Braz. Chem. Soc. 2021, 32(5), 953-963

Use of Paper Spray Mass Spectrometry for Determining the Chemical Profile of Green Cavendish Banana (Musa AAA) Peel and Pulp Flours and Evaluation of Its Functional Potential

Anna Cláudia F. e Loyola ; Viviane D. M. Silva; Mauro R. Silva; Camila G. Rodrigues; Amanda N. dos Santos ; Júlio O. F. Melo ; Rodinei Augusti ; Camila A. Fante

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Functional potential of green Cavendish banana (Musa AAA) peel and pulp flours obtained by three drying methods.

https://dx.doi.org/10.21577/0103-5053.20200243

Published online: December 15, 2020

 

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J. Braz. Chem. Soc. 2021, 32(5), 964-977

Iron Nitrate Modified Cotton and Polyester Textile Fabric Applied for Reactive Dye Removal from Water Solution

Jenny S. Komatsu ; Beatriz M. Motta; Rodolfo S. Tiburcio ; Ana M. Pereira Neto; Pol W. G. de Pape; Dalmo Mandelli; Wagner A. Carvalho

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Reactive dye adsorbent based on textile fabric, applicable over a wide pH range was developed. Spent adsorbents were used to produce mesoporous magnetic activated carbon with elemental Fe species.

https://dx.doi.org/10.21577/0103-5053.20200244

Published online: December 16, 2020

 

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J. Braz. Chem. Soc. 2021, 32(5), 978-988

An Online Solid Phase Extraction-Liquid Chromatography Tandem Mass Spectrometry Method for the Analysis of Parabens in Urban Waters

Simone Nascimento ; Quezia Cass

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Solid phase extraction (SPE) online method working as direct injection by liquid chromatography tandem mass spectrometry (LC-MS/MS) analyzing parabens in ng L-1 levels in urban waters.

https://dx.doi.org/10.21577/0103-5053.20200246

Published online: December 21, 2020

 

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J. Braz. Chem. Soc. 2021, 32(5), 989-1001

Effects of Polycyclic Aromatic Hydrocarbon Pendant-Armed Ligands on the Catecholase Activity of Dinuclear Copper(II) Complexes

Marcos P. da Silva; Renata S. Heying; Letícia I. da Silva; Adailton J. Bortoluzzi; Rosely A. Peralta ; Ademir Neves

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Three new copper(II) complexes presented great catalytic activity through 3,5-di-tert-butylcatechol oxidation model and affinity with deoxyribonucleic acid from calf thymus (CT-DNA).

https://dx.doi.org/10.21577/0103-5053.20200247

Published online: December 22, 2020

 

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Crystal Data (CIF)

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J. Braz. Chem. Soc. 2021, 32(5), 1002-1008

Electrochemical Preparation and Evaluation of Cytotoxic Activity of Methoxyl‑oxo‑biseugenol, a New Oxidized Derivative of Biseugenol

Flavia T. da Silva; Kaio S. Gomes ; Fabricio C. Machado; Leticia L. Loureiro; Luiz R. Travassos; Tereza S. Martins; João Henrique G. Lago ; Fernanda F. Camilo

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Electrochemical oxidation of biseugenol in methanol afforded a new oxidized derivative, methoxyl-oxo-biseugenol, which exhibited higher cytotoxic activity than biseugenol.

https://dx.doi.org/10.21577/0103-5053.20210002

Published online: January 6, 2021

 

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J. Braz. Chem. Soc. 2021, 32(5), 1009-1016

New Pair of 2-Amino-naphthoxazoles Derived from β-Lapachone: Synthesis, Spectral Evaluation and Crystal Structure

Leonardo A. Silva ; Emanoel Hottes; Ari M. da Silva; Luan M. S. Freire; Guilherme P. Guedes ; Aurélio B. B. Ferreira

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2-Amino-naphthoxazole was synthesized using a simple method, but unprecedented in the literature.

https://dx.doi.org/10.21577/0103-5053.20210003

Published online: January 6, 2021

 

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Total access: 1233


J. Braz. Chem. Soc. 2021, 32(5), 1017-1029

Design, Synthesis and Antifungal Activity of New Schiff Bases Bearing 2-Aminothiophene Derivatives Obtained by Molecular Simplification

Isadora S. Luna; Wendell W. Neves; Reginaldo G. de Lima-Neto; Amanda P. B. Albuquerque; Maíra G. R. Pitta; Moacyr J. B. M. Rêgo; Rejane P. Neves; Marcus T. Scotti ; Francisco J. B. Mendonça-Junior

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Molecular simplification reduced "molecular obesity" and resulted in 2-aminothiophenes with good druglikeness, pharmacokinetics and antifungal profiles.

https://dx.doi.org/10.21577/0103-5053.20210004

Published online: January 7, 2021

 

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J. Braz. Chem. Soc. 2021, 32(5), 1030-1039

Astaxanthin Recovery from Shrimp Residue by Solvent Ethanol Extraction Using Choline Chloride:Glycerol Deep Eutectic Solvent as Adjuvant

Cleidijane A. dos Santos; Carlos E. A. Padilha; Karla S. F. S. C. Damasceno; Pedro I. P. Leite; Ana C. J. de Araújo; Priscila R. Freitas; Érica A. Vieira; Angela M. T. M. Cordeiro; Francisco C. de Sousa Jr. ; Cristiane F. de Assis

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Astaxanthin recovery from shrimp residue by solvent ethanol extraction using choline chloride:glycerol deep eutectic solvent as adjuvant.

https://dx.doi.org/10.21577/0103-5053.20210005

Published online: January 8, 2021

 

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J. Braz. Chem. Soc. 2021, 32(5), 1040-1050

Incorporation of Fluorescent Dyes in Electrospun Chitosan/Poly(ethylene oxide)

Cristiane Guellis; Ariane R. S. Rossin; Guilherme G. Bessegato; Douglas C. Dragunski ; Reinaldo A. Bariccatti; Cleber A. Lindino

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Fluorescence dyes were successfully incorporated into chitosan-poly(ethylene oxide) electrospun films and showed emission processes in solid-state.

https://dx.doi.org/10.21577/0103-5053.20210006

Published online: January 12, 2021

 

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J. Braz. Chem. Soc. 2021, 32(5), 1051-1059

Porosity of CHA Zeolite Driving the Formation of Polyaromatic Coke Species in the Methanol to Olefins Reaction

Bianca R. Florindo ; Gabriel L. Catuzo; Leandro Martins

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The figure shows entrapped species of coke that lead to the selective formation of olefins.

https://dx.doi.org/10.21577/0103-5053.20210008

Published online: January 14, 2021

 

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Total access: 845


J. Braz. Chem. Soc. 2021, 32(5), 1060-1069

Chemical Constituents and Cytotoxic Activity of Rhinella jimi (Anura: Bufonidae)

Evaldo S. Monção Filho; Yara P. F. Pio; Mariana H. Chaves; Paulo M. P. Ferreira; Mariluce G. Fonseca; Cláudia Pessoa; Daisy J. B. Lima; Bruno Q. Araújo; Gerardo M. Vieira Jr.

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Preparation of the venom extracts from Rhinella jimi species, followed by evaluation of cytotoxity activity and identification by ultra-performance liquid chromatography coupled to mass spectrometry (UPLC-MS) and direct insertion mass spectrometry (DI-MS/MS).

https://dx.doi.org/10.21577/0103-5053.20210009

Published online: January 18, 2021

 

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Total access: 1112


J. Braz. Chem. Soc. 2021, 32(5), 1070-1081

Synthesis, Characterization, and Application of Europium(III) Complexes as Luminescent Markers of Banknotes

Clebson J. Macrino; Elias M. Silva; Victor R. Cunha; Victor R. Fonseca; Álvaro Cunha Neto ; Joyce R. Araújo; Valdemar
Lacerda Jr. ; Wanderson Romão

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The present work aims to use three europium(III) luminescent complexes as markers for identification of real banknotes through the luminescence of the complexes and identification of their chemical profiles using the laser desorption ionization mass spectrometry (LDI (±) MS) technique.

https://dx.doi.org/10.21577/0103-5053.20210010

Published online: January 19, 2021

 

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Total access: 960


J. Braz. Chem. Soc. 2021, 32(5), 1082-1099

Synthesis, Hypoglycemic Effect, Antimicrobial and Molecular Docking Studies of Organotin(IV) Complexes Derived from N-Phthalimido β-Amino Acid Derivatives

Muhammad M. Ahmed ; Nagina N. Riaz; Muhammad Kashif ; Muhammad Ashfaq; Muhammad N. Arshad; Muhammad Sajid

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Novel series of organotin(IV) complexes has been prepared with new β-amino acid derivatives. The characterization of these compounds was accomplished by elemental analysis, Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance (1H, 13C, 119Sn) spectroscopy, mass spectrometry and molecular docking studies. The in vitro antibacterial, antioxidant and in vivo hypoglycemic screening on rabbits were also carried out.

https://dx.doi.org/10.21577/0103-5053.20210011

Published online: January 19, 2021

 

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Total access: 771


J. Braz. Chem. Soc. 2021, 32(5), 1100-1110

Chemoenzymatic Synthesis of Apremilast: A Study Using Ketoreductases and Lipases

Kimberly B. Vega; Daniel M. V. Cruz; Artur R. T. Oliveira; Marcos R. da Silva; Telma L. G. de Lemos; Maria C. F. Oliveira; Ricardo D. S. Bernardo ; Jackson R. de Sousa; Geancarlo Zanatta; Fábio D. Nasário; Anita J. Marsaioli; Marcos C. de Mattos

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A straightforward chemoenzymatic synthesis of apremilast has been developed involving the lipase-mediated preparation of a
(R)-sulfonylethanol as a key step.

https://dx.doi.org/10.21577/0103-5053.20210012

Published online: January 22, 2021

 

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Total access: 1241


J. Braz. Chem. Soc. 2021, 32(5), 1111-1119

In vivo and in vitro Volatile Constituents of the Flowers of Xylopia aromatica by HS-SPME/GC-MS

João G. M. Junqueira ; Michelle N. G. do Nascimento; Lucas G. da Costa; Lincoln L. Romualdo; Francisco W. B. de Aquino; Mustapha N. Abubakar; Ana P. Terezan; Gustavo O. S. Cunha ; Vanessa G. P. Severino

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Headspace solid-phase microextraction (HS-SPME) combined with gas chromatography-mass spectrometry (GC-MS) were applied to evaluate the volatile organic compounds (VOCs) of X. aromatica flowers extracted via in vivo and in vitro sampling.

https://dx.doi.org/10.21577/0103-5053.20210013

Published online: January 26, 2021

 

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Total access: 976


J. Braz. Chem. Soc. 2021, 32(5), 1120-1130

Thallium Associated with Manganese Ore Tailings in a Deactivated Mine in the Western Region of Bahia, Brazil

Jorge Luís O. Santos ; Giuliana M. G. Bueno; Eder L. M. Flores; Oldair D. Leite ; Clayton R. Janoni; Luis G. Carvalho; Ana Maria P. dos Santos

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The natural occurrence of the Tl in soil and ore tailings samples from a deactivated manganese mine, in Western Bahia, Brazil, and its influence and risk to environmental health.

https://dx.doi.org/10.21577/0103-5053.20210014

Published online: January 26, 2021

 

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Short Report J. Braz. Chem. Soc. 2021, 32(5), 1131-1136

Pseudo-Univariate Calibration Based on NIR Spectroscopy in the Determination of Anthocyanins and Antioxidant Activity in Grape Juices

Karla K. Beltrame; Thays R. Gonçalves; Paulo H. Março; Sandra T. M. Gomes; Makoto Matsushita; Patrícia Valderrama

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Grape juice: a proposal to determine anthocyanins and antioxidant activity based on near-infrared (NIR) spectroscopy and independent components analysis (ICA).

https://dx.doi.org/10.21577/0103-5053.20210007

Published online: January 12, 2021

 

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Total access: 773

Online version ISSN 1678-4790 Printed version ISSN 0103-5053
Journal of the Brazilian Chemical Society
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University of Campinas - UNICAMP
13083-970 Campinas-SP, Brazil

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