JBCS

16:39, Thu Nov 21

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vol. 32, No. 6, 2021, p. 1137-1299

 

Nanotechnology has several applications and possibilities. CdTe-based semiconductors functionalized with thiolic compounds allow the production of fluorescent nanoprobes soluble in aqueous media that can be used in different systems. In this work, to determine cationic proteins in biological and medication samples, exploring the bioconjugation concept between the nanoprobe and protein (protamine), with a change in spectroscopic properties. Details are presented in the Article Bioconjugation between CdTe Quantum Dots and a Cationic Protein: An Analytical Method to Determine Protamine in Drug and Urine Samples by Karolayne R. da Costa, Uéslen Rocha, Tasso O. Sales, Josué C. C. Santos on page 1151.


Cover Article
J. Braz. Chem. Soc. 2021, 32(6), 1151-1161

Bioconjugation between CdTe Quantum Dots and a Cationic Protein: An Analytical Method to Determine Protamine in Drug and Urine Samples

Karolayne R. da Costa; Uéslen Rocha; Tasso O. Sales; Josué C. C. Santos

How to cite this article

Nanotechnology has several applications and possibilities. CdTe-based semiconductors functionalized with thiolic compounds allow the production of fluorescent nanoprobes soluble in aqueous media that can be used in different systems. In this work, to determine cationic proteins in biological and medication samples, exploring the bioconjugation concept between the nanoprobe and protein (protamine), with a change in spectroscopic properties. Details are presented in the Article Bioconjugation between CdTe Quantum Dots and a Cationic Protein: An Analytical Method to Determine Protamine in Drug and Urine Samples by Karolayne R. da Costa, Uéslen Rocha, Tasso O. Sales, Josué C. C. Santos on page 1151.

https://dx.doi.org/10.21577/0103-5053.20210016

Published online: February 3, 2021
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Articles J. Braz. Chem. Soc. 2021, 32(6), 1137-1142

Different Degradation Patterns of Chiral Contaminant Enantiomers: Paclobutrazol as a Case Study

Hao-Ming Guo; Yue Zhao; Mei-Nan Ouyang; Zhong-Hua Yang

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Paclobutrazol residue in soil showed enantioselective degradation.

https://dx.doi.org/10.21577/0103-5053.20210001

Published online: January 6, 2021

 

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J. Braz. Chem. Soc. 2021, 32(6), 1143-1150

A Gas Chromatography Method for Simultaneous Quantification of Inorganic Gases and Light Hydrocarbons Generated in Thermochemical Processes

Valdislaine M. Silva; José S. Pessoa Filho; Raquel M. F. Sousa ; Solidônio R. Carvalho; Valério L. Borges; Cassius R. N. Ferreira; Maria Clara V. M. Starling; Alam G. Trovó

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A method for simultaneous determination of inorganic gases and light hydrocarbons by gas chromatography using thermal conductivity and flame ionization detectors.

https://dx.doi.org/10.21577/0103-5053.20210015

Published online: January 27, 2021

 

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J. Braz. Chem. Soc. 2021, 32(6), 1151-1161

Bioconjugation between CdTe Quantum Dots and a Cationic Protein: An Analytical Method to Determine Protamine in Drug and Urine Samples

Karolayne R. da Costa; Uéslen Rocha; Tasso O. Sales; Josué C. C. Santos

How to cite this article

 

CdTe quantum dots (QD-CdTe) functionalized with mercaptosuccinic acid were synthesized in an aqueous medium for protamine determination based on an on-off strategy.

https://dx.doi.org/10.21577/0103-5053.20210016

Published online: February 3, 2021

 

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Total access: 1833


J. Braz. Chem. Soc. 2021, 32(6), 1162-1172

Trypanocidal Activity and Increased Solubility of Benznidazole Incorporated in PEG 4000 and Its Derivatives

Lucas R. D. Sousa; Maria Luíza S. Azevedo; Dayana F. Rocha; Ângela L. Andrade; Tatiane R. Amparo; Orlando D. H. dos Santos; Janaína B. Seibert; Luciano R. Pereira; Paula M. A. Vieira; Cláudia M. Carneiro; Ana Paula M. Barboza; Bernardo R. A. Neves; Policarpo A. Sales Jr.; Silvane M. F. Murta; Kátia M. Novacka; Viviane M. R. dos Santos

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The present figure describes the preparation and characterization of PEG 4000 and derivatives with benznidazole, as well as evaluates their trypanocidal activity.

https://dx.doi.org/10.21577/0103-5053.20210017

Published online: February 8, 2021

 

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J. Braz. Chem. Soc. 2021, 32(6), 1173-1185

Expedient Microwave-Assisted Synthesis of Bis(n)-lophine Analogues as Selective Butyrylcholinesterase Inhibitors: Cytotoxicity Evaluation and Molecular Modelling

Viktor S. Câmara; Ana Julia Soares; Brunella Biscussi ; Ana Paula Murray ; Isabella A. Guedes ; Laurent E. Dardenne ; Thaís C. Ruaro; Aline R. Zimmer; Marco A. Ceschi

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Bis(n)-lophine analogues were synthesized through one-pot four-component reaction performed in a microwave reactor. The compounds were strongly selective to butyrylcholinesterase (BuChE), predicted to interact deeply into the binding cavity and present no cytotoxicity.

https://dx.doi.org/10.21577/0103-5053.20210018

Published online: February 8, 2021

 

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J. Braz. Chem. Soc. 2021, 32(6), 1186-1192

Gold Nanorods Capped with Different Ammonium Bromide Salts on the Catalytic Chemical Reduction of p-Nitrophenol

Francyelle M. de Oliveira ; Lucas R. B. A. Nascimento ; Claudia M. S. Calado ; Simoni M. P. Meneghetti ;
Monique G. A. da Silva ; Mario R. Meneghetti

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Chemical reduction of p-nitrophenol with NaBH4, using gold nanorods capped with different ammonium bromide surfactants as catalysts.

https://dx.doi.org/10.21577/0103-5053.20210019

Published online: February 9, 2021

 

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J. Braz. Chem. Soc. 2021, 32(6), 1193-1202

Optimization and Study of the Response Surface of Properties for the Synthesis of ZSM-5 Zeolites with Hierarchical Pore Structure Obtained by Desilication

Holman J. Mesa; Arnaldo C. Faro Jr.; Victor O. Rodrigues

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Optimal conditions for the synthesis of ZSM-5 zeolites with hierarchical pore structure were obtained using a 23 factorial design.

https://dx.doi.org/10.21577/0103-5053.20210020

Published online: February 10, 2021

 

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J. Braz. Chem. Soc. 2021, 32(6), 1203-1212

Effect of Preparation Additives on the Antimicrobial Activity and Cytotoxicity of Polypyrrole

Yslaine A. de Almeida ; Diego F. Bispo ; Monalisa M. Montalvão ; Karina O. Mota; Cristiane B. Corrêa ; Iara F. Gimenez

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Polypyrrole with additives or modifying agents has a potential antibacterial and biocompatible agent in the regeneration of tissue.

https://dx.doi.org/10.21577/0103-5053.20210021

Published online: February 11, 2021

 

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J. Braz. Chem. Soc. 2021, 32(6), 1213-1221

On the Use of a TiO2 Sol-Gel for Horseradish Peroxidase Enzyme Immobilization for Development of an Amperometric Biosensor

Carolina G. da Rocha ; Carolina V. Uliana ; Hideko Yamanaka

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Horseradish peroxidase enzyme (HRP) is immobilized on the surface of pencil graphite electrode (PGE) using a TiO2 sol-gel film;
5-aminosalicylic acid (5-ASA) acts as an electron mediator of the catalytic cycle of HRP in the presence of H2O2, resulting in a reduction current proportional to 5-ASA concentration.

https://dx.doi.org/10.21577/0103-5053.20210022

Published online: February 12, 2021

 

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J. Braz. Chem. Soc. 2021, 32(6), 1222-1238

Study of Crystallization and Composition on Silicon Oxycarbide (SiOC) and Silicon Boron Oxycarbide (SiBOC) Ceramics Obtained from Alkoxysilanes Precursors

Mariana G. Segatelli ; Patricia M. Sanchez; Lívia R. C. Silva; Maria A. Silva; César R. T. Tarley ; Paulo R. C. da Silva;
Emerson S. Ribeiro

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SiC and Cgraphitic phases were produced in different proportions into ceramics by varying the organic substituent in B-containing alkoxysilanes precursors.

https://dx.doi.org/10.21577/0103-5053.20210023

Published online: February 17, 2021

 

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J. Braz. Chem. Soc. 2021, 32(6), 1239-1248

Alcoholmeter as a Simple and Accessible Way for Ethanol Determination in Alcohol-Based Hand Sanitizers

Priscila L. S. Estevão; Franciely G. Colodi; Lucas C. L. do Carmo ; Maria de Fátima C. Santos; Andersson Barison;
Caroline R. M. D'Oca; Noemi Nagata; Rilton A. de Freitas

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We demonstrate that alcoholmeter could be used as an inexpensive, handy, and fast alternative method to determine ethanol content in alcohol-based hand sanitizers, improving the quality control of such commercial product.

https://dx.doi.org/10.21577/0103-5053.20210026

Published online: February 19, 2021

 

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Total access: 1493


J. Braz. Chem. Soc. 2021, 32(6), 1249-1258

Comparative Study of Degradation of Reactive Dyes and Decolorization and Detoxification in Aqueous Solution Applying DyP Peroxidases Isolated from Saccharomonospora viridis (SviDyP) and Thermobifida fusca (TfuDyp)

Carolline Schreiber; Franklin M. F. de Souza; Paulo C. de Jesus ; Eduardo Zapp; Patrícia B. Brondani

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Dye-decolorizing peroxidases (DyPs) isolated from Saccharomonospora viridis (SviDyP) and Thermobifida fusca (TfuDyp) were studied in the degradation, decolorization and detoxification of reactive dye solutions. The SviDyP showed impressive results.

https://dx.doi.org/10.21577/0103-5053.20210027

Published online: February 25, 2021

 

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J. Braz. Chem. Soc. 2021, 32(6), 1259-1269

Reduced Graphene Oxide/Ruthenium Oxide Hexacyanoferrate Nanocomposite for Electrochemical Determination of Ethanol in Commercial Samples

Pedro H. S. Borges; Edson Nossol

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Reduced graphene oxide/ruthenium oxide hexacyanoferrate (rGO/RuOHCF) modified electrode shows synergic electrochemical activity and ample linear range for ethanol electrocatalytic oxidation via amperometry coupled with batch injection analysis (BIA) system.

https://dx.doi.org/10.21577/0103-5053.20210028

Published online: February 26, 2021

 

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J. Braz. Chem. Soc. 2021, 32(6), 1270-1276

Liquid Phase Nitration of Benzene Catalyzed by a Novel Salt of Molybdovanadophosphoric Heteropolyacid

Jianan Liu; Yanan Wang; Shuwen Gong ; Wenzeng Duan; Xianqiang Huang

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The novel salt showed excellent catalytic performance in the nitration of benzene, including good reusability. The yield of nitrobenzene can reach 82.5% under optimized reaction conditions.

https://dx.doi.org/10.21577/0103-5053.20210029

Published online: March 3, 2021

 

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J. Braz. Chem. Soc. 2021, 32(6), 1277-1285

Chemical Characteristics and Antioxidant Activity of Astaxanthin Extracted from Shrimp Residues Using Soybean Oil

Denise M. L. e Silva; Karla S. F. S. C. Damasceno; Penha P. C. Ribeiro; Maristela A. Alcântra; Angela M. T. M. Cordeiro; Thaís S. Passos; Francisco C. de Sousa Jr. ; Cristiane F. de Assis

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Extracting astaxanthin from the shrimp residue shells and the shrimp waste from meal.

https://dx.doi.org/10.21577/0103-5053.20210030

Published online: March 3, 2021

 

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J. Braz. Chem. Soc. 2021, 32(6), 1286-1293

Electrochemical Behavior of Unusual Dimeric Flavonoids Isolated from Fridericia platyphylla

Jessyane R. do Nascimento; Geyse A. C. Ribeiro; Silvia H. P. Serrano; Roberto B. de Lima; Auro A. Tanaka ; Iranaldo S. da Silva ; Cláudia Q. da Rocha

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Electrochemical study of three unusual dimeric flavonoids in a Brazilian plant Fridericia platyphylla.

https://dx.doi.org/10.21577/0103-5053.20210031

Published online: March 4, 2021

 

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Short Report J. Braz. Chem. Soc. 2021, 32(6), 1294-1299

A Greener Enzymatic Oligoesterification of Biobased Renewable Synthons

Juan Villavicencio ; Ferley Orozco ; Ricardo Benitez ; Jaime Martin ; Giovanni Rojas

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Polyesters of xylitol and succinic acid were prepared by enzyme-catalyzed esterification using limonene as solvent yielding from 70 to 75% of pure product.

https://dx.doi.org/10.21577/0103-5053.20210024

Published online: February 19, 2021

 

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Online version ISSN 1678-4790 Printed version ISSN 0103-5053
Journal of the Brazilian Chemical Society
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