JBCS

18:14, Thu Nov 21

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vol. 34, No. 1, 2023, p. 1-152

 

The efficient encapsulation of N,N-diethyl-3-methylbenzamide (DEET), an insect-repellent compound, in mineral oil-in-water emulsions was achieved using a tailored combination of surfactants, cationic cellulose, and silica nanoparticles. The combined action of these non-toxic materials as emulsion stabilizers allowed a sustained release of DEET for at least six hours, showing the potential of these formulations for an extended repellent effect. Details are presented in the Article Efficient Encapsulation and Controlled Release of N,N-Diethyl-3-methylbenzamide (DEET) from Oil-in-Water Emulsions Stabilized by Cationic Nanocellulose and Silica Nanoparticles by Luis M. Gutierrez-Beleño, Vincenzo Calabrese, Janet L. Scott, Karen J. Edler and Aurora Pérez-Gramatges on page 13.


Cover Article
J. Braz. Chem. Soc. 2023, 34(1), 13-24

Efficient Encapsulation and Controlled Release of N,N-Diethyl-3-methylbenzamide (DEET) from Oil-in-Water Emulsions Stabilized by Cationic Nanocellulose and Silica Nanoparticles

Luis M. Gutierrez-Beleño ; Vincenzo Calabrese ; Janet L. Scott ; Karen J. Edler ; Aurora Pérez-Gramatges

How to cite this article

The efficient encapsulation of N,N-diethyl-3-methylbenzamide (DEET), an insect-repellent compound, in mineral oil-in-water emulsions was achieved using a tailored combination of surfactants, cationic cellulose, and silica nanoparticles. The combined action of these non-toxic materials as emulsion stabilizers allowed a sustained release of DEET for at least six hours, showing the potential of these formulations for an extended repellent effect. Details are presented in the Article Efficient Encapsulation and Controlled Release of N,N-Diethyl-3-methylbenzamide (DEET) from Oil-in-Water Emulsions Stabilized by Cationic Nanocellulose and Silica Nanoparticles by Luis M. Gutierrez-Beleño, Vincenzo Calabrese, Janet L. Scott, Karen J. Edler and Aurora Pérez-Gramatges on page 13.

https://dx.doi.org/10.21577/0103-5053.20220084

Published online: June 9, 2022
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Editorial J. Braz. Chem. Soc. 2023, 34(1), 1

Expectations for a New Scenario in Science and Technology

Paulo Cezar Vieira

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https://dx.doi.org/10.21577/0103-5053.20230006

Total access: 253


Articles J. Braz. Chem. Soc. 2023, 34(1), 2-12

Catalysts Derived from Thermal Treatments of Hydrocalumite-Type Compounds: Synthesis and Application in Transesterification Reactions

Roberta G. Prado ; Addila G. S. Corrêa; Joyce F. Rodrigues; Cristiane A. Scaldaferri; Fabiana P. de Sousa; Vânya M. D. Pasa; Vera R. L. Constantino; Frederico G. Pinto; Jairo Tronto

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Synthesis of heterogeneous catalysts derived from thermal treatments on hydrocalumite-type compounds intercalated with chloride and nitrate anions was carried out. The prepared catalysts were used in transesterification reactions to produce biodiesel.

https://dx.doi.org/10.21577/0103-5053.20220082

Published online: June 1, 2022

 

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J. Braz. Chem. Soc. 2023, 34(1), 13-24

Efficient Encapsulation and Controlled Release of N,N-Diethyl-3-methylbenzamide (DEET) from Oil-in-Water Emulsions Stabilized by Cationic Nanocellulose and Silica Nanoparticles

Luis M. Gutierrez-Beleño ; Vincenzo Calabrese ; Janet L. Scott ; Karen J. Edler ; Aurora Pérez-Gramatges

How to cite this article

 

Stabilization of oil-in-water emulsions containing N,N-diethyl-3-methylbenzamide (DEET)  using oppositely charged cationic cellulose nanofibrils (CCNF) and silica nanoparticles (SiNP) to allow extended and sustained release of DEET.

https://dx.doi.org/10.21577/0103-5053.20220084

Published online: June 9, 2022

 

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Total access: 1565


J. Braz. Chem. Soc. 2023, 34(1), 25-35

Synthesis and Evaluation of Antibacterial Activity of 1,2,3-Triazole and Ether Derivatives of Paeonol

Laura Patricia R. Figueroa; Nayara A. dos Santos; Pedro Henrique O. Santiago; Wanderson Romão ; Valdemar Lacerda Junior ; Javier Ellena ; Ana Camila Micheletti; Warley S. Borges

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Paeonol derivatives were synthesized and their biological activities tested.

https://dx.doi.org/10.21577/0103-5053.20220085

Published online: June 13, 2022

 

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Total access: 1102


J. Braz. Chem. Soc. 2023, 34(1), 36-53

Evaluation of the Properties of LaNiO3 Material Prepared by the Modified Proteic Method for Adsorption of Environmental Contaminants

Jéssica A. S. Lemos; Iasmin A. Ribeiro; Marcelo J. B. Souza; Anne M. Garrido Pedrosa

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The removal of environmental contaminants such as Turquoise Blue dye from an aqueous medium can be made using LaNiO3 material, with perovskite structure, and occurs due to electrostatic interactions between both.

https://dx.doi.org/10.21577/0103-5053.20220086

Published online: June 14, 2022

 

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Total access: 733


J. Braz. Chem. Soc. 2023, 34(1), 54-62

Lipid Profile of Human Milk in Different Lactation Stages Submitted to Pasteurization, Lyophilization and Spray-Drying Processes

Vanessa J. C. Neia ; Patrícia D. S. Santos; Christyna B. G. Tavares ; Meliana G. Paula ; Silvio C. Costa; Joana M. V. Zacarias; Josiane B. Alencar; Roberta Silveira ; Oscar O. Santos ; Jeane E. L. Visentainer ; Jesuí V. Visentainer

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Effect of pasteurization, lyophilization and spray-drying processes on the lipid profile of colostrum, transitional and mature human milk.

https://dx.doi.org/10.21577/0103-5053.20220087

Published online: June 23, 2022

 

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Total access: 846


J. Braz. Chem. Soc. 2023, 34(1), 63-68

Nicotine as a Catalyst for Chlorination Promoted by Hypochlorous Acid: Experimental and Theoretical Studies

Valdecir F. Ximenes ; Nathalia M. Pavan; Aguinaldo R. de Souza; Gabriel A. Barros; Nelson H. Morgon

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Hypochlorous acid (HClO) is an endogenous oxidant, and nicotine is the primary addictive component of tobacco smoke. Nicotine catalyzes the chlorination of biomolecules. This paper describes the mechanism of the catalytic effect of nicotine.

https://dx.doi.org/10.21577/0103-5053.20220088

Published online: June 27, 2022

 

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Total access: 765


J. Braz. Chem. Soc. 2023, 34(1), 69-82

The Contribution of Meteorological Parameters and the COVID-19 Partial Lockdown on Air Quality in Rio de Janeiro, Brazil

Karmel Beringui ; Elizanne P. S. Justo ; Luciana M. B. Ventura ; Ruan G. S. Gomes; Vinícius Lionel-Mateus ;
Alex H. De La Cruz ; Ana Carolina L. B. de Almeida; Michelle B. Ramos; Julio Angeles Suazo; Pedro H. R. Valle; Adriana Gioda

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After a partial lockdown decree in Rio de Janeiro, reductions in pollutant sources were the main factor explaining lower concentrations of criteria pollutants. Meteorological conditions, similar to previous year, favor pollutant dispersion by sea breeze.

https://dx.doi.org/10.21577/0103-5053.20220089

Published online: June 27, 2022

 

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Total access: 949


J. Braz. Chem. Soc. 2023, 34(1), 83-91

Influence of Refinery Asphalt Residue Addition on Flow: A Study Using Waxy Model-System

Ana Carla F. Valente; Rita C. P. Nunes; Elizabete F. Lucas

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Synergistic effect of poly(ethylene-co-vinyl acetate) (EVA) copolymer and asphaltic residue from refinery on the reduction of pour point.

https://dx.doi.org/10.21577/0103-5053.20220090

Published online: June 28, 2022

 

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Total access: 605


J. Braz. Chem. Soc. 2023, 34(1), 92-102

Bimetallic Au-Pd/α-MoO3 Catalyst with High Oxygen Vacancies for Selective Oxidation of Cinnamyl Alcohol

Renilma C. Sousa; Jussara M. da Silva; Jean C. S. Costa ; Carla V. R. de Moura ; Edmilson M. de Moura

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The α-MoO3 support employed in this work allows the synthesis of potentially active and selective Au-Pd catalysts for the aerobic oxidation of cinnamyl alcohol under base and solvent-free conditions.

https://dx.doi.org/10.21577/0103-5053.20220091

Published online: June 30, 2022

 

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Total access: 836


J. Braz. Chem. Soc. 2023, 34(1), 103-111

Carbon Dots from Pilosocereus gounellei for Fluorimetric Determination of Tannin in Tea Using a Flow-Batch System

Kelly D. Silva ; Stéfani I. E. Andrade ; Marcelo B. Lima ; Severino S. Monte-Filho ; Mário C. U. Araújo ; Ricardo A. C. Lima

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Carbon dots from Pilosocereus gounellei were used to develop a fast, low-cost, eco-friendly fluorescence flow-batch method for the determination of tannins in teas.

https://dx.doi.org/10.21577/0103-5053.20220092

Published online: July 4, 2022

 

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Total access: 694


J. Braz. Chem. Soc. 2023, 34(1), 112-123

Study of Catalytic Pyrolysis of Biomass Sorghum (Sorghum bicolor L. Moench) Using Design of Experiments and Surface Response Methodology

Diego M. Costa; Maria L. F. Simeone ; Rafael A. C. Parrella; Isabel C. P. Fortes

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Samples of biomass sorghum BRS716 were submitted to fast catalytic pyrolysis to produce a bio-oil rich in hydrocarbon or phenolic compounds after optimizing the suitable critical process parameters using a response surface methodology approach.

https://dx.doi.org/10.21577/0103-5053.20220093

Published online: July 4, 2022

 

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Total access: 686


J. Braz. Chem. Soc. 2023, 34(1), 124-134

Encoding of Luminescent Ink Markers Using Low-Level Data Fusion and Chemometrics

Caroline R. Carneiro ; Isabela B. Serwy; Carolina S. Silva ; Ingrid T. Weber

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Chemometric tools make it possible to differentiate the luminescent markers inserted in the ink, creating a document encoding process.

https://dx.doi.org/10.21577/0103-5053.20220094

Published online: July 5, 2022

 

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Total access: 746


J. Braz. Chem. Soc. 2023, 34(1), 135-145

Honey of Tetragonisca angustula from Southwestern Bahia: Influence of Seasonality on the Physicochemical Profile and Glioma Cell Inhibitory Effect

Adrianne B. Ferreira ; Cleber G. Novaes ; Hion O. de Jesus; Julita Maria P. Borges; Florisvaldo S. Ramos; Anderson J. Pereira; Djalma M. de Oliveira; Rosane M. Aguiar

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Tetragonisca angustula stingless bee honey collected in dry and rainy periods were subjected to analysis of physicochemical parameters, phenolic content, identification of phenolic compounds by high-performance liquid chromatography with ultraviolet detection (HPLC-UV) and glioma cell inhibitory effect.

https://dx.doi.org/10.21577/0103-5053.20220095

Published online: July 5, 2022

 

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Total access: 858


Short Report J. Braz. Chem. Soc. 2023, 34(1), 146-152

Phenolic Compounds from Leaves of Cariniana estrellensis (Raddi) Kuntze (Lecythidaceae): A Brazilian Atlantic Forest Tree

Angelica N. Tiepo ; Isabel D. Coutinho; Guilherme O. Machado; Halley C. Oliveira ; José Antonio Pimenta ; Liliane Marcia M. Henning ; Luiz Alberto Colnago; Renata Stolf-Moreira

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Cariniana estrellensis seedlings are used in forest restoration programs in the Atlantic Forest biome. We used rapid analysis by nuclear magnetic resonance and liquid chromatography coupled to diode array, charged aerosol, and mass detection to provide the first data on secondary metabolism from C. estrellensis. We identified hydrolysable tannins, hydroxycinnamic acids, and flavonoids.

https://dx.doi.org/10.21577/0103-5053.20220083

Published online: June 14, 2022

 

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Total access: 814

Online version ISSN 1678-4790 Printed version ISSN 0103-5053
Journal of the Brazilian Chemical Society
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