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vol. 34, No. 5, 2023, p. 615-753

 

Camellia sinensis extract from different origins were used to prepare iron nanomaterials by a green and sustainable route. Fenton degradation of methyl orange mediated by the nanomaterials led to complete degradation, which was favored by the pH lowering promoted by the polyphenols. The iron oxides obtained after annealing were not so effective, confirming the importance of the polyphenols to enhance Fenton efficiency. Details are presented in the Article Effect of Camellia sinensis Origin and Heat Treatment in the Iron Oxides Nanomaterials Composition and Fenton Degradation of Methyl Orange by Raissa T. Franco, Ana Luisa Silva, Yordy E. Licea, Mariella Alzamora, Dalber R. Sánchez and Nakédia M. F. Carvalho on page 694.


Cover Article
J. Braz. Chem. Soc. 2023, 34(5), 694-704

Effect of Camellia sinensis Origin and Heat Treatment in the Iron Oxides Nanomaterials Composition and Fenton Degradation of Methyl Orange

Raissa T. Franco ; Ana Luisa Silva ; Yordy E. Licea ; Mariella Alzamora; Dalber R. Sánchez; Nakédia M. F. Carvalho

How to cite this article

Camellia sinensis extract from different origins were used to prepare iron nanomaterials by a green and sustainable route. Fenton degradation of methyl orange mediated by the nanomaterials led to complete degradation, which was favored by the pH lowering promoted by the polyphenols. The iron oxides obtained after annealing were not so effective, confirming the importance of the polyphenols to enhance Fenton efficiency. Details are presented in the Article Effect of Camellia sinensis Origin and Heat Treatment in the Iron Oxides Nanomaterials Composition and Fenton Degradation of Methyl Orange by Raissa T. Franco, Ana Luisa Silva, Yordy E. Licea, Mariella Alzamora, Dalber R. Sánchez and Nakédia M. F. Carvalho on page 694.

https://dx.doi.org/10.21577/0103-5053.20220140

Published online: November 10, 2022
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Review J. Braz. Chem. Soc. 2023, 34(5), 615-640

Combining Fluorescent Quantum Dots with Molecularly Imprinted Polymers for the Screening of both Emerging and Classical Environmental Pollutants: A Review

Shakeel Zeb; Javier E. L. Villa; Ademar Wong; Sabir Khan ; Sajjad Hussain; Maria D. P. T. Sotomayor

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Graphically representation of quantum dots (QDs) coated molecular imprinted polymer sensor for the determination of emerging and classical pollutants. Nanoscale QD materials are suitable for fluorescence analysis. The modification with quantum dots provides many advantages such as rapid detection, highly selective and easily operational.

https://dx.doi.org/10.21577/0103-5053.20230015

Published online: January 25, 2023

 

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Articles J. Braz. Chem. Soc. 2023, 34(5), 641-652

The Use of Single Crystal X-ray Diffraction Technique for Characterization of 25I-NBOMe and 25R-NBOH (R = Cl, I, Br, Et) in Forensic Application

Maria C. C. Lucena; Karen P. S. Lopes; Alejandro P. Ayala; Laura M. T. Vidal; Thiago I. B. Lopes; Nágila M. P. S. Ricardo

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The single crystal X-ray diffraction is a non-destructive and promising technique as a qualitative method for identifying benzylphenethylamine substances such as 25I-NBOMe and 25R-NBOH (R = Cl, I, Br, Et).

https://dx.doi.org/10.21577/0103-5053.20220130

Published online: October 19, 2022

 

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J. Braz. Chem. Soc. 2023, 34(5), 653-663

Sugarcane Bagasse Fibers Derivatives and Their Application in Chitosan-Based Composite Films for NPK Fertilizer Release

Lucas Luiz Messa ; Gabriela Aparecida Contieri; Roselena Faez

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Development of biopolymers-based composites from a renewable feedstock for slowing NPK fertilizer release.

https://dx.doi.org/10.21577/0103-5053.20220135

Published online: October 27, 2022

 

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Total access: 817


J. Braz. Chem. Soc. 2023, 34(5), 664-672

Baru Seed Extracted Oil (Dipteryx alata Vog.): Chemical Composition and Thermal and Oxidative Stability

Linamarys A. O. Paulo; Raquel N. Fernandes; Kelly M. B. Gandra; Valéria P. R. Minim; Luis A. Minim; Renato Grimaldi; Márcia C. T. R. Vidigal

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This study investigates the physicochemical properties, chemical and bioactive composition, thermal and oxidative stability, and interfacial properties of baru seed oil, oleaginous species native to the Brazilian Cerrado.

https://dx.doi.org/10.21577/0103-5053.20220136

Published online: November 4, 2022

 

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J. Braz. Chem. Soc. 2023, 34(5), 673-683

Synthesis, Characterization, and Anion Exchange Reactions of Zn2Cr Layered Double Hydroxides Intercalated with Acetate and Chloride

Anne Raquel Sotiles; Marco T. Grassi ; Mayara P. dos Santos; Luis Gustavo S. Lameu; Fernando Wypych

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Zn2Cr layered double hydroxides intercalated with chloride or acetate were synthesized and the exchange reactions investigated.

https://dx.doi.org/10.21577/0103-5053.20220137

Published online: November 7, 2022

 

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Total access: 700


J. Braz. Chem. Soc. 2023, 34(5), 684-693

Mathematical Mapping Study of Synthetic Antioxidants Behavior in Biodiesel: Application of the Self-Organized Feature Map (SOFM) and Multilayer Perceptron (MLP)

Marco A. J. Clemente; Heloisa H. P. Silva; Julia W. Campos; Nathan F. Silva; Eduardo G. Sousa; Ana C. G. Mantovani; Karina B. Angilelli; Dionisio Borsato

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Self-organizing feature maps (SOFM) and multilayer perceptron (MLP) neural networks were applied to evaluate the protection capacity of tert-butylhydroquinone (TBHQ), butylhydroxyanisole (BHA), and butylhydroxytoluene (BHT) antioxidants against the biodiesel oxidation reaction.

https://dx.doi.org/10.21577/0103-5053.20220139

Published online: November 8, 2022

 

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J. Braz. Chem. Soc. 2023, 34(5), 694-704

Effect of Camellia sinensis Origin and Heat Treatment in the Iron Oxides Nanomaterials Composition and Fenton Degradation of Methyl Orange

Raissa T. Franco ; Ana Luisa Silva ; Yordy E. Licea ; Mariella Alzamora; Dalber R. Sánchez; Nakédia M. F. Carvalho

How to cite this article

 

Green iron oxide nanomaterials were prepared from Camellia sinensis extracts of different regions and annealed at 900 şC, which promoted the phase transformation from amorphous to crystalline α-Fe2O3, FePO4 and Fe3PO7. The as-prepared iron nanomaterials were more efficient in the heterogeneous Fenton degradation of methyl orange due to natural pH lowering to around 3.

https://dx.doi.org/10.21577/0103-5053.20220140

Published online: November 10, 2022

 

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Total access: 1233


J. Braz. Chem. Soc. 2023, 34(5), 705-712

Production of Silver Nanoparticles Mediated by Aqueous Extracts of Tucumă (Astrocaryum aculeatum) Pulp

Sidney S. dos Santos ; Ricardo A. A. de Couto; Ingrid R. da Silva; Marcia Regina M. Aouada; Vera R. L. Costantino ; Luiz P. da Costa ; Gustavo F. Perotti

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Green synthesis of silver nanoparticles mediated by aqueous extracts of tucumă pulp, an Amazonian resource.

https://dx.doi.org/10.21577/0103-5053.20220141

Published online: November 11, 2022

 

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J. Braz. Chem. Soc. 2023, 34(5), 713-724

Extraction Induced by Microemulsion Breaking and Square Wave Voltammetry: A Promising Union to Monitor Cd, Pb and Cu in Biodiesel

Cristian H. Krause ; Alexandre B. Schneider ; Márcia M. da Silva; Marina B. Mazzei; Leandro Kolling ; Fernando N. Leal

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Cadmium, lead and copper determination in biodiesel by square wave voltammetry with portable potentiostat, after extraction induced by microemulsion breaking.

https://dx.doi.org/10.21577/0103-5053.20220142

Published online: November 16, 2022

 

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J. Braz. Chem. Soc. 2023, 34(5), 725-733

Use of Ionic Liquid-Based Ultrasound Assisted Liquid-Liquid Extraction of Phenols from Aqueous Fractions of Seed Bio-Oil

Solange C. A. Cerqueira; Laryssa M. Santos; Antonia R. S. Gois; Cleide M. F. Soares; Brenno A. DaSilveira Neto; Lisiane S. Freitas

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This work investigates the extraction phenols in aqueous-phase pyrolysis of guava seeds, using ultrasonic assisted liquid-liquid extraction with ionic liquids (UALLE-IL).

https://dx.doi.org/10.21577/0103-5053.20220143

Published online: November 17, 2022

 

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J. Braz. Chem. Soc. 2023, 34(5), 734-744

Nickel Nanoparticles Anchored on Bentonite Clay for Methane Decomposition with Ordered Carbon as a Product

Rayssa J. B. Motta ; Camila B. Dornelas; Rusiene M. de Almeida

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Synthesis and characterization using different nickel oxide concentrations on bentonite to produce ordered carbon by methane decomposition.

https://dx.doi.org/10.21577/0103-5053.20220144

Published online: November 18, 2022

 

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Total access: 710


Short Report J. Braz. Chem. Soc. 2023, 34(5), 745-753

Synthesis of Isatins and Oxindoles Derivatives as SARS-CoV-2 Inhibitors Evaluated through Phenotypic Screening with Vero Cells

Cintia M. C. F. Lima; Lúcio H. Freitas-Junior; Carolina B. Moraes; Cecília G. Barbosa; Till Opatz; Mauricio M. Victor

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In this work, we performed the synthesis of twenty-seven substituted isatins, 3-hydroxy bis-oxindoles and isoindigos and evaluated against severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) using a phenotypic screening assay.

https://dx.doi.org/10.21577/0103-5053.20220138

Published online: November 8, 2022

 

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Total access: 876

Online version ISSN 1678-4790 Printed version ISSN 0103-5053
Journal of the Brazilian Chemical Society
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