JBCS

17:55, Thu Nov 21

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vol. 34, No. 9, 2023, p. 1215-1372

 

Plastic debri is an environmental and health problem that is catching growing attention from scientists and society in general. Here is proposed a two in one approach to reuse this white pollution, mainly due to commercial polystyrene, turning it into a new porous material that is able to reduce organic compounds like 4-nitrophenol thanks to added nanotechnology, silver nanocatalyst. It is demonstrated that those final foams are able to preserve thermal and plasmonic catalytic features of the silver nanoparticles, opening opportunities for a new approach of reuse of plastic waste to create new multifunctional porous materials. Details are presented in the Article Silver Nanocatalyst Supported on Waste-Based Polystyrene Foam for Thermal and Plasmonic Reduction of p-Nitrophenol by Welida T. A. da Silva, Geovânia C. de Assis, Roberta A. de Jesus, Rayssa J. B. Motta, Luiz Fernando R. Ferreira, Yolice Patricia M. Ruiz, André Galembeck, Ricardo Schneider and Rodrigo J. de Oliveira on page 1317.


Cover Article
J. Braz. Chem. Soc. 2023, 34(9), 1317-1332

Silver Nanocatalyst Supported on Waste-Based Polystyrene Foam for Thermal and Plasmonic Reduction of p-Nitrophenol

Welida T. A. da Silva; Geovânia C. de Assis ; Roberta A. de Jesus ; Rayssa J. B. Motta ; Luiz Fernando R. Ferreira; Yolice Patricia M. Ruiz; André Galembeck; Ricardo Schneider; Rodrigo J. de Oliveira

How to cite this article

Plastic debri is an environmental and health problem that is catching growing attention from scientists and society in general. Here is proposed a two in one approach to reuse this white pollution, mainly due to commercial polystyrene, turning it into a new porous material that is able to reduce organic compounds like 4-nitrophenol thanks to added nanotechnology, silver nanocatalyst. It is demonstrated that those final foams are able to preserve thermal and plasmonic catalytic features of the silver nanoparticles, opening opportunities for a new approach of reuse of plastic waste to create new multifunctional porous materials. Details are presented in the Article Silver Nanocatalyst Supported on Waste-Based Polystyrene Foam for Thermal and Plasmonic Reduction of p-Nitrophenol by Welida T. A. da Silva, Geovânia C. de Assis, Roberta A. de Jesus, Rayssa J. B. Motta, Luiz Fernando R. Ferreira, Yolice Patricia M. Ruiz, André Galembeck, Ricardo Schneider and Rodrigo J. de Oliveira on page 1317.

https://dx.doi.org/10.21577/0103-5053.20230044

Published online: March 28, 2023
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Articles J. Braz. Chem. Soc. 2023, 34(9), 1215-1223

Assessment of Ora-Pro-Nobis (Pereskia aculeata Miller) Leaves Shelf-Life in Different Conditions by Using NIR Spectroscopy and Augmented Matrices with Chemometrics

Fernanda L. Furlan; Makoto Matsushita; Aline Coqueiro ; Paulo Henrique Março; Patrícia Valderrama

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Ora-pro-nobis leaves: a strategy for the shelf-life evaluation.

https://dx.doi.org/10.21577/0103-5053.20230022

Published online: February 17, 2023

 

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J. Braz. Chem. Soc. 2023, 34(9), 1224-1235

Statistical Analysis of the Chemical Composition of Concrete Slurry Waste: A Case Study of Sedimentation Tanks from Concrete Batching Plants in Manaus-Brazil

Jéssica Raíssa M. Guimarães ; Yves Nathan M. de Faria ; Mateus F. de Oliveira ; Lizandro Manzato ; Cláudia C. Silva

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Cement sludge samples were submitted to wavelength dispersive X-ray fluorescence (WD-XRF) analysis; in view of the results obtained, the possible applications of this residue were evaluated.

https://dx.doi.org/10.21577/0103-5053.20230034

Published online: March 14, 2023

 

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J. Braz. Chem. Soc. 2023, 34(9), 1236-1249

Physicochemical Properties of Superabsorbent Hydrogels Formed by Polyelectrolytic Complexation of Carboxymethylcellulose-Chitosan at Basic pH

Gustavo M. da Silva; Ivana L. M. Ferreira ; Marcia P. M. Costa; Rafael F. P. Rocha

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Sample prepared at basic pH remained intact after immersion in water, proving the polyelectrolyte complexes (PEC's) formation by carboxymethylcellulose-chitosan complexation.

https://dx.doi.org/10.21577/0103-5053.20230035

Published online: March 14, 2023

 

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J. Braz. Chem. Soc. 2023, 34(9), 1250-1261

Ursolic Acid Derivatives Down Regulate Inflammatory Mediators

Elaine C. Scherrer; Ydia M. Valadares; Caio C. S. Alves ; Alessandra P. Carli; Bárbara G. R. Fernandes; Paloma E. Carvalho; Karla A. Ramos; Maiara R. Salvador; Jeferson G. da Silva; Fernando S. Silva; Ângelo M. L. Denadai; Sandra B. R. Castro

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Ursolic acid derivatives reduce inflammatory mediators (nitric oxide (NO), tumor necrosis factor (TNF), interleukin-6 (IL-6) and nuclear factor kappa B (NF-κB)), and decrease the carrageenan paw edema.

https://dx.doi.org/10.21577/0103-5053.20230036

Published online: March 14, 2023

 

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J. Braz. Chem. Soc. 2023, 34(9), 1262-1272

Stable and Thermo-Responsive Dextran Sulfate-Graft-PNIPAm Amphiphilic Nanoparticles for Potential Target Methotrexate Delivery

Aline T. dos Santos; Emerson L. da Silva; Raquel C. Montenegro; Jeanlex S. de Sousa; Regina C. M. de Paula ; Judith P. A. Feitosa

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The dextran sulfate-graft-poly(N-isopropylacrylamide) (PNIPAm) is amphiphilic, stable, and non-cytotoxic. It forms nanoparticles spontaneously at temperatures close to that of the human body. It incorporates and releases a hydrophobic and extremely toxic drug, used in the treatment of cancer and rheumatoid arthritis, methotrexate, with potential targeting release due to the presence of dextran sulfate.

https://dx.doi.org/10.21577/0103-5053.20230037

Published online: March 15, 2023

 

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J. Braz. Chem. Soc. 2023, 34(9), 1273-1283

Synthesis and Anticancer Activity of Homodimeric Morita-Baylis-Hillman Adducts Based on
3-Hydroxyindolin-2-one Core

Maísa C. Coelho ; Aleff Castro ; Tayná R. Olegário ; Rodrigo Cristiano ; Boniek G. Vaz ; Gabriel F. dos Santos ;
Lucas S. Machado ; Gardênia C. G. Militão ; Paulo B. N. da Silva ; Mário L. A. A. Vasconcellos ; Claudio G. Lima-Junior

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Ten novel dimeric Morita-Baylis-Hillman adducts from ethylene glycol diacrylate are reported. Some of them exhibited an increase in anticancer activity and selectivity, compared to the respective monomeric adducts.

https://dx.doi.org/10.21577/0103-5053.20230038

Published online: March 16, 2023

 

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J. Braz. Chem. Soc. 2023, 34(9), 1284-1292

Photocatalytic Degradation of Bentazon Pesticide by a Fe2O3-TiO2 Composite Catalyst Irradiated by UVA, UVB, and Natural Light

Cristian S. Braga; Guilherme G. Bessegato; Keiti Maestre; Fernando R. Espinoza-Quiñones; Helton J. Alves; Leandro C. da Silva;
Renato Eising; Reinaldo A. Bariccatti

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Photocatalysis is a useful tool for environmental remediation. Bentazon molecules can be decomposed into simpler substances by the action of the catalyst (Fe2O3-TiO2) and sunlight (22,000 lux).

https://dx.doi.org/10.21577/0103-5053.20230039

Published online: March 16, 2023

 

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Total access: 784


J. Braz. Chem. Soc. 2023, 34(9), 1293-1302

Molecular Modeling Studies of β-Sitosterol Extract from Miconia burchellii Triana (Melastomataceae) from Brazilian Cerrado

Marianna C. Silva ; Vitor S. Duarte; Lóide O. Sallum ; Gracielle O. S. Cunha; Jean M. F. Custodio; Allen G. Oliver;
Josana C. Peixoto; Antônio C. S. Menezes; Hamilton B. Napolitano

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Molecular modeling studies from Cerrado plant.

https://dx.doi.org/10.21577/0103-5053.20230040

Published online: March 20, 2023

 

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Total access: 699


J. Braz. Chem. Soc. 2023, 34(9), 1303-1308

Theoretical Study of 2,6-Dichloro-3-methyl-1,4-benzoquinone Interacting with Graphene

Leandro C. Sobrinho; Silvete Guerini

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Electronic band structure and plot of the local density of states for 2,6-dichloro-3-methyl-1,4-benzoquinone molecule interacting graphene in configuration most stable.

https://dx.doi.org/10.21577/0103-5053.20230041

Published online: March 23, 2023

 

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J. Braz. Chem. Soc. 2023, 34(9), 1309-1316

Featured Properties of the Adsorption of Tebuconazole on Ag Surface Characterized through SERS Spectroscopy

Rafael de Oliveira ; Antonio Carlos Sant'Ana

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Adsorption geometries for tebuconazole on silver surface, in different hot spots, were proposed based on studies involving surface-enhanced Raman scattering (SERS) spectroscopy.

https://dx.doi.org/10.21577/0103-5053.20230042

Published online: March 23, 2023

 

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J. Braz. Chem. Soc. 2023, 34(9), 1317-1332

Silver Nanocatalyst Supported on Waste-Based Polystyrene Foam for Thermal and Plasmonic Reduction of p-Nitrophenol

Welida T. A. da Silva; Geovânia C. de Assis ; Roberta A. de Jesus ; Rayssa J. B. Motta ; Luiz Fernando R. Ferreira; Yolice Patricia M. Ruiz; André Galembeck; Ricardo Schneider; Rodrigo J. de Oliveira

How to cite this article

 

Polystyrene waste, also known as white pollution, has been repurposed as support for silver nanocatalyst. Those nanofoams were able to convert p-nitrophenol into aminophenol under plasmonic excitation.

https://dx.doi.org/10.21577/0103-5053.20230044

Published online: March 28, 2023

 

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Total access: 1577


J. Braz. Chem. Soc. 2023, 34(9), 1333-1346

Controlled Release of Rutin from Babassu Coconut Mesocarp Starch Films

Liane M. Carvalho ; Cicero W. B. Bezerra ; Claudia Q. da Rocha ; Letícia N. de Oliveira ; Luna N. Vasconcelos ; Sirlane A. A. Santana

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Schematic representation of the production of babassu mesocarp films loaded with Arrabidaea brachypoda leaf extract and controlled release assay at pH 7.4.

https://dx.doi.org/10.21577/0103-5053.20230045

Published online: March 30, 2023

 

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J. Braz. Chem. Soc. 2023, 34(9), 1347-1352

Evaluation of the Metabolic Production from the Co-Culture of Saccharicola sp. and Botryosphaeria parva, an Endophytic Fungi Associated with Eugenia jambolana Lam.

Mayra F. Costa; Maiara S. Borges; Vanessa M. Chapla ; Carolina R. Biasetto; Isabele R. Nascimento ; Vanderlan S. Bolzani; Angela R. Araujo

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A new carboxylic acid and eight known compounds were isolated from co-culture of Saccharicola sp. and Botryosphaeria parva, an endophytic fungi in Eugenia jambolana.

https://dx.doi.org/10.21577/0103-5053.20230046

Published online: March 31, 2023

 

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J. Braz. Chem. Soc. 2023, 34(9), 1353-1359

New Catalysts Derived from Natural Products as Highly Stereoselective Chiral Inductors for Diethylzinc Addition to Aromatic Aldehydes

Celso L. Wosch; Ricardo Labes; Kahlil S. Salome; Vitor S. Melo; Renan R. Schorr; Palimécio G. Guerrero Jr.; Nathalya K. Lima; Gustavo Frensch; Beatriz H. L. N. S. Maia; Francisco A. Marques

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Chiral ligands derived from (+)-camphor and (-)-fenchone for the addition of diethylzinc to aromatic aldehydes showed enantiomeric excess up to 96%.

https://dx.doi.org/10.21577/0103-5053.20230047

Published online: April 4, 2023

 

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J. Braz. Chem. Soc. 2023, 34(9), 1360-1372

Voltammetric Study on the Electrowinning of Cobalt in the Presence of Additives

Danielle C. de Castro ; Iranildes D. dos Santos ; Marcelo B. Mansur; Achilles J. B. Dutra

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Cyclic voltammetry was applied to investigate the influence of some organic and inorganic additives on cobalt electrowinning since it is an energy-intensive process and requires an industrially acceptable cobalt deposit production at low operating costs.

https://dx.doi.org/10.21577/0103-5053.20230048

Published online: April 6, 2023

 

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Total access: 687

Online version ISSN 1678-4790 Printed version ISSN 0103-5053
Journal of the Brazilian Chemical Society
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