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vol. 35, No. 4, 2024, p. 1-16

 

The cover art depicts the molecular structure of one of the various lanthanide-based coordination compounds explored in this work. The beam of light irradiating from the complex illustrates its emissive feature arising from the association between spectroscopic properties of both lanthanide ion and ligand. The magnetic field lines reference the single-ion magnet property of the complex, evidencing its multifunctional nature. Details are presented in the Article Photoluminescent and Magnetic Properties of Mononuclear Lanthanide-Based Compounds Containing the Zwitterionic Form of 4-Picolinic Acid as a Ligand by Esther S. Areas, Bruno P. Rodrigues, Ana Carolina C. do Nascimento, Henrique C. Silva Junior, Glaucio B. Ferreira, Fabio S. Miranda, Flávio Garcia, Syed H. Safeer, Stéphane Soriano and Guilherme P. Guedes on e-20230160.


Cover Article
J. Braz. Chem. Soc. 2024, 35(4), 1-15

Photoluminescent and Magnetic Properties of Mononuclear Lanthanide-Based Compounds Containing the Zwitterionic Form of 4-Picolinic Acid as a Ligand

Esther S. Areas; Bruno P. Rodrigues; Ana Carolina C. do Nascimento; Henrique C. Silva Junior ; Glaucio B. Ferreira ;
Fabio S. Miranda; Flávio Garcia ; Syed H. Safeer; Stéphane Soriano; Guilherme P. Guedes

How to cite this article

The cover art depicts the molecular structure of one of the various lanthanide-based coordination compounds explored in this work. The beam of light irradiating from the complex illustrates its emissive feature arising from the association between spectroscopic properties of both lanthanide ion and ligand. The magnetic field lines reference the single-ion magnet property of the complex, evidencing its multifunctional nature. Details are presented in the Article Photoluminescent and Magnetic Properties of Mononuclear Lanthanide-Based Compounds Containing the Zwitterionic Form of 4-Picolinic Acid as a Ligand by Esther S. Areas, Bruno P. Rodrigues, Ana Carolina C. do Nascimento, Henrique C. Silva Junior, Glaucio B. Ferreira, Fabio S. Miranda, Flávio Garcia, Syed H. Safeer, Stéphane Soriano and Guilherme P. Guedes on e-20230160.

https://dx.doi.org/10.21577/0103-5053.20230160

Published online: September 27, 2023
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Articles J. Braz. Chem. Soc. 2024, 35(4), 1-8

Novel Phenylpropanoid Derivative from Euploca procumbens (Mill.) Diane & Hilger with Potential Anti-Inflammatory Activity

George L. D. dos Santos ; Francisca S. V. Lins; Yuri M. do Nascimento; Thalisson A. de Souza; Luiza C. F. Opretzka ;
Cristiane F. Villarreal; Ana C. F. de Albuquerque; Lucas S. Abreu ; Fernando M. dos Santos Junior ; José I. M. de Melo;
Ivana M. Fechine; Raimundo Braz-Filho ; Josean F. Tavares ; Marcelo S. da Silva

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The current work describes structural assignment and biological activity of a novel phenyl propanoid isolated from Euploca procumbens.

https://dx.doi.org/10.21577/0103-5053.20230150

Published online: September 4, 2023

 

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J. Braz. Chem. Soc. 2024, 35(4), 1-15

Exploring Urease Inhibition by Coumarin Derivatives through in silico and in vitro Methods

Marciéli Fabris ; Priscila G. Camargo ; Mariana L. Silva ; Talis U. Silva ; Sérgio P. Machado ; Carlos R. Rodrigues ;
Camilo H. S. Lima ; Magaly G. Albuquerque ; Marcelle L. F. Bispo

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Synthesis of coumarins and in vitro evaluation against Canavalia ensiformis urease. Investigation of interactions with C. ensiformis and Helicobacter pylori ureases by in silico studies.

https://dx.doi.org/10.21577/0103-5053.20230151

Published online: September 5, 2023

 

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J. Braz. Chem. Soc. 2024, 35(4), 1-12

Chocolates Produced with Unroasted and Roasted Cocoa Beans: A Comparative Study of the Preservation of Bioactive Compounds

Rebeca R. V. Onelli; Josane C. de Jesus; Lucas C. C. Reis; Isabel C. S. Alves; Leandro S. Santos ; Sibelli P. B. Ferrão

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Use of roasted and unroasted cocoa beans for chocolate production.

https://dx.doi.org/10.21577/0103-5053.20230152

Published online: September 5, 2023

 

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J. Braz. Chem. Soc. 2024, 35(4), 1-9

Redox-Activated NO Release in Monolayer Regime

Millena P. Ferreira; Walysson G. Pereira; Vitória S. Dibo; Dieric S. Abreu; Luiz G. F. Lopes; Izaura C. N. Diógenes ; Tércio F. Paulo

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As proved by scanning electrochemical microscopy (SECM), NO0 is released in monolayer regime from a RuII nitrosyl complex containing 1,4-dtihiane (1,4-dt) adsorbed on gold through the sulfur atom.

https://dx.doi.org/10.21577/0103-5053.20230153

Published online: September 5, 2023

 

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J. Braz. Chem. Soc. 2024, 35(4), 1-15

A Multi-Geochemical Characterization to Evaluate Anthropogenic Contamination in Marine Sediments from Port of Suape, Northeast of Brazil

Ana Flávia B. de Oliveira; Bruna R. S. Gomes; Rebeca S. França; Thayane Cristina S. Moreira; Alex S. Moraes;
Giovana A. Bataglion ; Jandyson M. Santos

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Anthropogenic contamination of the Port of Suape based on the determination of sterols, aliphatic hydrocarbons (AHs), polycyclic aromatic hydrocarbons (PAHs), trace metals and As.

https://dx.doi.org/10.21577/0103-5053.20230154

Published online: September 11, 2023

 

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Total access: 686


J. Braz. Chem. Soc. 2024, 35(4), 1-11

Characterization and Biological Activity of Native and Sulfated Noni (Morinda citrifolia Linn.) Pectin

Denilton G. Santos; Arcelina P. Cunha; Ana C. B. Ribeiro; Débora H. A. Brito; Luciana M. R. Alenca; Davi F. Farias; Ana F. F. U. Carvalho; João A. C. Sousa; Luzia K. A. M. Leal; Nayara Lopes; Rosa E. C. Linhares; Carlos Nozawa; Antonia F. J. Uchoa; Maria E. N. P. Ribeiro ; Nágila M. P. S. Ricardo

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Pectin extracted from noni (Morinda citrifolia Linn.) and its sulfated derivative were chemically characterized to assess its in vivo and in vitro toxicity, in addition to anti-inflammatory and antiviral activity.

https://dx.doi.org/10.21577/0103-5053.20230156

Published online: September 13, 2023

 

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Total access: 592


J. Braz. Chem. Soc. 2024, 35(4), 1-12

Novel Flavanone Naringenin Derivative with Anti-Inflammatory Activity

Rodrigo O. S. de Souza; Lívia C. R. Hilgenberg; Ana C. S. Pinto; Renyer A. Costa; Fernanda G. Simplicio ; Emerson S. Lima

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The condensation reaction between naringenin and aminoguanidine gave rise to a hydrazinecarboximidamide, which showed anti-inflammatory activity in vivo, in vitro and in silico.

https://dx.doi.org/10.21577/0103-5053.20230157

Published online: September 13, 2023

 

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Total access: 622


J. Braz. Chem. Soc. 2024, 35(4), 1-9

Evaluation of Lipid Composition and Nutritional Quality of Olive Oil Varieties Using ESI-MS, GC-FID and Chemometrics Techniques

Alisson L. Figueiredo; Michele C. Silva; Jessica S. Pizzo ; Patrícia D. S. Santos; Luciana P. Manin ; Mariana S. Leôncio;
Jesuí V. Visentainer ; Oscar O. Santos

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The utilization of gas chromatography and mass spectrometry techniques, in conjunction with statistical tools such as principal component analysis (PCA), offers a powerful method to accurately determine and differentiate the lipid profiles of diverse olive samples.

https://dx.doi.org/10.21577/0103-5053.20230158

Published online: September 22, 2023

 

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J. Braz. Chem. Soc. 2024, 35(4), 1-16

Reactivity Studies and Synthetic Strategies Towards the Preparation of New Hydrophilic Indirubin-Triazole-Based Compounds

Ana Flávia dos S. Fuzaro; Frederico Henrique do C. Ferreira; Gabriela L. P. Suhett; Luiz Antônio S. Costa ;
Richard Michael Grazul; Mauro V. de Almeida; Eloah P. Ávila

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Synthesis of indirubins linked to triazole sugar derivatives; the reactivity of the indirubin skeleton and molecular docking studies are also presented.

https://dx.doi.org/10.21577/0103-5053.20230159

Published online: September 27, 2023

 

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Total access: 599


J. Braz. Chem. Soc. 2024, 35(4), 1-15

Photoluminescent and Magnetic Properties of Mononuclear Lanthanide-Based Compounds Containing the Zwitterionic Form of 4-Picolinic Acid as a Ligand

Esther S. Areas; Bruno P. Rodrigues; Ana Carolina C. do Nascimento; Henrique C. Silva Junior ; Glaucio B. Ferreira ;
Fabio S. Miranda; Flávio Garcia ; Syed H. Safeer; Stéphane Soriano; Guilherme P. Guedes

How to cite this article

 

The lanthanide-based compounds irradiated at 280 nm are fluorescent species due to the key role played by the 4picH (zwitterionic form of the 4-picolinic acid) ligand as a sensitizer. The dysprosium derivative is a potential white-light emitter and behaves as a field-induced single-ion magnet.

https://dx.doi.org/10.21577/0103-5053.20230160

Published online: September 27, 2023

 

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Total access: 1439


J. Braz. Chem. Soc. 2024, 35(4), 1-12

Development of an Electroanalytical Method for Ronidazole Determination in Environmental and Food Matrices Using Boron-Doped Diamond Electrode

Guilherme Bettio; Leonardo L. Okumura; Renê C. Silva; Tiago A. Silva

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Boron-doped diamond electrode was applied for the voltammetric determination of ronidazole via cathodic process in water and milk samples.

https://dx.doi.org/10.21577/0103-5053.20230162

Published online: September 28, 2023

 

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Total access: 542


J. Braz. Chem. Soc. 2024, 35(4), 1-9

Niobium Oxide Photocatalytically Oxidizes Ammonia in Water at Ambient Conditions

Welman C. Elias; Chelsea A. Clark; Kimberly N. Heck; Jacob H. Arredondo; Bo Wang; Andras Toro; László Kürti; Michael S. Wong

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In this work, we developed a simple materials synthesis procedure to increase the photocatalytic activity of niobium oxide (Nb2O5) for ammonia oxidation by > 10× without using noble metals.

https://dx.doi.org/10.21577/0103-5053.20230163

Published online: October 10, 2023

 

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Total access: 668


J. Braz. Chem. Soc. 2024, 35(4), 1-10

Potentially Toxic Elements in Commercial Soap and Powder Detergent Samples

Briyitte Sofia S. Torres; Ihasmyn S. Nunes; Nattany Tayany G. de Paula; Ana Paula S. Paim

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Acid digestion of soap samples for subsequent determination of Cd, Mg, Pb and Zn by inductively coupled plasma optical emission spectroscopy (ICP OES).

https://dx.doi.org/10.21577/0103-5053.20230164

Published online: October 11, 2023

 

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J. Braz. Chem. Soc. 2024, 35(4), 1-6

FeCl3-Catalyzed Cross-Coupling for Improving the Synthesis of Upadacitinib

Ziling Li; Chundiao Shi; Shengchang Xiang; Chulong Liu; Ximing Zheng

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A FeCl3/p-aminophenol catalyst system was used to improve ethyl group introduction in the synthesis of upadacitinib.

https://dx.doi.org/10.21577/0103-5053.20230165

Published online: October 16, 2023

 

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Total access: 568


J. Braz. Chem. Soc. 2024, 35(4), 1-7

Study of the Three-Dimensional Structure of Tryptophan Zipper Peptides through 1H NMR Chemical Shifts Calculations

Ana Carolina F. de Albuquerque ; Fernando M. dos Santos Jr.

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We investigated the applicability of nuclear magnetic resonance chemical shift calculations in the analysis of three-dimensional structures of peptides, using tryptophan zipper 1 as a study model.

https://dx.doi.org/10.21577/0103-5053.20230166

Published online: October 17, 2023

 

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J. Braz. Chem. Soc. 2024, 35(4), 1-9

Capillary Zone Electrophoresis with Diode-Array Detection as a Tool to Monitor Variations in the Concentration of Organic Acids from the Tricarboxylic Acid Cycle in Human Urine

Riani L. Salvio; Hugo Tolentino; Alexandra Latini; Marcelo F. Ronsoni; Gustavo A. Micke

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Changes in metabolism may be reflected in the tricarboxylic acid (TCA) cycle intermediates concentrations. It was validated and applied a method by capillary zone electrophoresis with diode array detector (CZE-DAD) to quantify the organic acids from the TCA cycle in human urine.

https://dx.doi.org/10.21577/0103-5053.20230167

Published online: October 17, 2023

 

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Total access: 513


J. Braz. Chem. Soc. 2024, 35(4), 1-7

Synthesis of a Series of 4H-Pyran Derivatives with Multicomponent Reaction in DBSA/H2O Microemulsion System

Jun Wang; Jialin Zang; Dan Li; Zhen Lv

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A series of 4H-pyran derivatives were synthesized through a three-component condensation reaction in a pot using aromatic aldehyde, cyclohexanedione, and malononitrile in the dodecyl benzenesulfonic acid/H2O microemulsion system.

https://dx.doi.org/10.21577/0103-5053.20230168

Published online: October 18, 2023

 

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Online version ISSN 1678-4790 Printed version ISSN 0103-5053
Journal of the Brazilian Chemical Society
JBCS Editorial and Publishing Office
University of Campinas - UNICAMP
13083-970 Campinas-SP, Brazil

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